The halogen bond

G Cavallo, P Metrangolo, R Milani, T Pilati… - Chemical …, 2016 - ACS Publications
The halogen bond occurs when there is evidence of a net attractive interaction between an
electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic …

Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers

P Peluso, B Chankvetadze - Chemical Reviews, 2022 - ACS Publications
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …

Halogen bonding in supramolecular chemistry

LC Gilday, SW Robinson, TA Barendt… - Chemical …, 2015 - ACS Publications
Supramolecular chemistry is “the chemistry of the intermolecular bond, covering the
structures and functions of the entities formed by association of two or more chemical …

[HTML][HTML] Applications of supramolecular anion recognition

N Busschaert, C Caltagirone, W Van Rossom… - Chemical …, 2015 - ACS Publications
The study of the complexation of anions, from its beginnings in the late 1960s and 1970s,(1-
3) has moved on from being an area solely of academic interest to a fundamental pillar of …

Chalcogen bonding: An overview

L Vogel, P Wonner, SM Huber - … Chemie International Edition, 2019 - Wiley Online Library
In the last few decades,“unusual” noncovalent interactions like anion‐π and halogen
bonding have emerged as interesting alternatives to the ubiquitous hydrogen bonding in …

Halogen, Chalcogen, Pnictogen, and Tetrel Bonding in Non‐Covalent Organocatalysis: An Update

D Jovanovic, M Poliyodath Mohanan… - Angewandte Chemie …, 2024 - Wiley Online Library
The use of noncovalent interactions based on electrophilic halogen, chalcogen, pnictogen,
or tetrel centers in organocatalysis has gained noticeable attention. Herein, we provide an …

Catalysis of organic reactions through halogen bonding

RL Sutar, SM Huber - ACS Catalysis, 2019 - ACS Publications
Halogen bonding, the noncovalent interaction based on electrophilic halogen substituents,
features very interesting properties, as illustrated by numerous applications continuously …

Beyond click chemistry–supramolecular interactions of 1, 2, 3-triazoles

B Schulze, US Schubert - Chemical Society Reviews, 2014 - pubs.rsc.org
The research on 1, 2, 3-triazoles has been lively and ever-growing since its stimulation by
the advent of click chemistry. The attractiveness of 1H-1, 2, 3-triazoles and their derivatives …

Frontiers in halogen and chalcogen‐bond donor organocatalysis

J Bamberger, F Ostler, OG Mancheño - ChemCatChem, 2019 - Wiley Online Library
Non‐covalent molecular interactions on the basis of halogen and chalcogen bonding
represent a promising, powerful catalytic activation mode. However, these “unusual” non …

Chalcogen bonding catalysis: tellurium, the last frontier?

P Pale, V Mamane - Chemistry–A European Journal, 2023 - Wiley Online Library
Chalcogen bonding (ChB) is the non‐covalent interaction occurring between chalcogen
atoms as Lewis acid sites and atoms or groups of atoms able to behave as Lewis bases …