Field induced single ion magnet behavior in Co II complexes in a distorted square pyramidal geometry
We report three CoII-based complexes with the general formula [CoII (L)(X) 2] by changing
the halide/pseudo-halide ions [X= NCSe (1SeCN); Cl (2Cl) and Br (3Br)]. The obtained τ5 …
the halide/pseudo-halide ions [X= NCSe (1SeCN); Cl (2Cl) and Br (3Br)]. The obtained τ5 …
Structures and magnetic anisotropies of two seven-coordinate Co (ii)–nitrate complexes showing slow magnetic relaxation
W Lv, L Chen, XT Chen, H Yan, Z Wang… - New Journal of …, 2023 - pubs.rsc.org
Two seven-coordinate Co (II)-nitrate complexes,[Co (tmpdc)(NO3) 2](1) and [Co
(tmpdt)(NO3) 2]· CH3CN (2)(tmpdc= N, N, N′, N′-tetramethyl-2, 6-pyridinedicarboxamide …
(tmpdt)(NO3) 2]· CH3CN (2)(tmpdc= N, N, N′, N′-tetramethyl-2, 6-pyridinedicarboxamide …
Trigonally Distorted Hexacoordinate Co (II) Single-Ion Magnets
By simple reactions involving various cobalt (II) carboxylates (acetate and in situ prepared
pivalate and 4-hydroxybenzoate salts) and neocuproine (neo), we were able to prepare …
pivalate and 4-hydroxybenzoate salts) and neocuproine (neo), we were able to prepare …
The Impact of Coordination Distortion on Magnetic Properties of Co (II) Single‐Ion Magnets With Trigonal Prism Coordination Geometry
G Peng, YB Peng, GX Zhou, RY Zhang… - Applied …, 2024 - Wiley Online Library
ABSTRACT Two Co (II) compounds [Co (abs) 2]· 2H2O (1) and [Co (pabs) 2](2)(Habs= N‐
(pyridine‐2′‐yl methylene)‐2‐aminobenzene sulfonic acid, Hpabs= N‐[(pyridine‐2 …
(pyridine‐2′‐yl methylene)‐2‐aminobenzene sulfonic acid, Hpabs= N‐[(pyridine‐2 …
Influence of F-position and solvent on coordination geometry and single ion magnet behavior of Co (ii) complexes
Y Chen, Q Yang, G Peng, YQ Zhang, XM Ren - Dalton Transactions, 2021 - pubs.rsc.org
Three mononuclear Co (II) complexes with the compositions of [Co (L1) 2](1),[Co (L2) 2
(CH3CN)](2) and [Co (L3) 2](3)(HL1= 2-((E)-(2-fluorobenzylimino) methyl)-4, 6 …
(CH3CN)](2) and [Co (L3) 2](3)(HL1= 2-((E)-(2-fluorobenzylimino) methyl)-4, 6 …
A robust low coordinate Co (II) catalyst for efficient conversion of CO2 into methanol under mild conditions
Compared to the Ru n+ (where n= 2 or 3) homogenous catalysts that convert CO 2 into
methanol, 3d metal catalysts (such as Fe n+, Co n+, and Mn n+) exhibit poor activity due to …
methanol, 3d metal catalysts (such as Fe n+, Co n+, and Mn n+) exhibit poor activity due to …
A Machine Learning Approach to Decipher the Origin of Magnetic Anisotropy in Three-Coordinate Cobalt Single-Ion Magnets
Single Molecule Magnets (SMMs) emulate permanent magnets and are highly regarded for
their role in compact information storage and molecular spintronics. Their behavior is …
their role in compact information storage and molecular spintronics. Their behavior is …
[PDF][PDF] Trigonally Distorted Hexacoordinate Co (II) Single-Ion Magnets. Materials 2022, 15, 1064
I Nemec, OF Fellner, B Indruchová, R Herchel - 2022 - academia.edu
By simple reactions involving various cobalt (II) carboxylates (acetate and in situ prepared
pivalate and 4-hydroxybenzoate salts) and neocuproine (neo), we were able to prepare …
pivalate and 4-hydroxybenzoate salts) and neocuproine (neo), we were able to prepare …