The [2+ 2] Cycloaddition‐Retroelectrocyclization (CA‐RE) Click Reaction: Facile Access to Molecular and Polymeric Push‐Pull Chromophores

T Michinobu, F Diederich - Angewandte Chemie International …, 2018 - Wiley Online Library
Abstract The [2+ 2] cycloaddition‐retroelectrocyclization (CA‐RE) reaction between electron‐
rich alkynes and electron‐deficient alkenes is an efficient procedure to create nonplanar …

Tetracyanobutadiene Bridged Push‐Pull Chromophores: Development of New Generation Optoelectronic Materials

Y Patil, H Butenschön, R Misra - The Chemical Record, 2023 - Wiley Online Library
This review describes the design strategies used for the synthesis of various
tetracyanobutadiene bridged donor‐acceptor molecular architectures by a click type [2+ 2] …

Non-planar push–pull chromophores

S Kato, F Diederich - Chemical communications, 2010 - pubs.rsc.org
The development of a unique class of non-planar push–pull chromophores by means of [2+
2] cycloaddition, followed by cycloreversion, of electron-deficient olefins, such as …

Copper (I) alkyne and alkynide complexes

H Lang, A Jakob, B Milde - Organometallics, 2012 - ACS Publications
Copper(I) Alkyne and Alkynide Complexes | Organometallics ACS ACS Publications C&EN CAS
Find my institution Log In Organometallics ACS Publications. Most Trusted. Most Cited. Most …

Photochromic Organometallics with a Dithienylethene (DTE) Bridge,[Y C C DTE C C Y](Y={MCp*(dppe)}): Photoswitchable Molecular Wire (M= Fe) versus …

Y Tanaka, T Ishisaka, A Inagaki, T Koike… - … A European Journal, 2010 - Wiley Online Library
Dinuclear acetylide‐type complexes bridged by a photochromic dithienylethene unit
(DTE),[Y C C DTE C C Y] 1 (Y={MCp*(dppe)}; Cp*= pentamethylcyclopentadienyl …

Ruthenium Complexes of C,C'-Bis(ethynyl)carboranes:  An Investigation of Electronic Interactions Mediated by Spherical Pseudo-aromatic Spacers

MA Fox, RL Roberts, TE Baines… - Journal of the …, 2008 - ACS Publications
The complexes [Ru (1-C⋮ C− 1, 10-C2B8H9)(dppe) Cp*](3a),[Ru (1-C⋮ C− 1, 12-
C2B10H11)(dppe) Cp*](3b),[{Ru (dppe) Cp*} 2 {μ-1, 10−(C⋮ C) 2− 1, 10-C2B8H8}](4a) and …

Modulation of Electronic Couplings within Ru2–Polyyne Frameworks

B **, IPC Liu, GL Xu, MMR Choudhuri… - Journal of the …, 2011 - ACS Publications
Dimers of [Ru2 (Xap) 4] bridged by 1, 3, 5-hexatriyn-diyl (Xap are 2-anilinopyridinate and its
aniline substituted derivatives),[Ru2 (Xap) 4] 2 (μ-C6)(1), were prepared. Compounds 1 …

Charge Delocalization in a Heterobimetallic Ferrocene−(Vinyl)Ru(CO)Cl(PiPr3)2 System

K Kowalski, M Linseis, RF Winter, M Zabel… - …, 2009 - ACS Publications
Ru (CH CHFc) Cl (CO)(P i Pr3) 2 (Fc= ferrocenyl,(η5-C5H4) Fe (η5-C5H5)), 1, has been
prepared by hydroruthenation of ethynylferrocene and characterized by NMR, IR, ESI-MS …

Magnetic perturbation of the redox potentials of localized and delocalized mixed-valence complexes

C Lapinte - Journal of Organometallic Chemistry, 2008 - Elsevier
The potential differences (ΔE) between the two one-electron events observed for
symmetrical mixed-valence (MV) complexes is generally used as a measurement of the …

1′, 1′′′-Bis (ethynyl) biferrocene as a Linking Group for Gold, Ruthenium, and Osmium Fragments: Synthesis, Solid State Structures, and Electrochemical, UV …

M Lohan, P Ecorchard, T Rüffer, F Justaud… - …, 2009 - ACS Publications
A series of organometallic mono-and disubstituted bis (alkynyl) biferrocenes of type (LnMC
C)(HC C) bfc (LnM=(η5-C5H5)(Ph3P) 2Ru (8a),(η5-C5H5)(Ph3P) 2Os (8b),(η5 …