Metal–organic framework magnets

AE Thorarinsdottir, TD Harris - Chemical reviews, 2020 - ACS Publications
Metal–organic frameworks represent the ultimate chemical platform on which to develop a
new generation of designer magnets. In contrast to the inorganic solids that have dominated …

Carbon-based Biradicals: Structural and Magnetic Switching

Y Ishigaki, T Harimoto, T Shimajiri, T Suzuki - Chemical Reviews, 2023 - ACS Publications
Sterically hindered C═ C double bonds often deform into a bent or twisted geometry. Thus,
many overcrowded ethylenes or anthraquinodimethanes can adopt multiple conformations …

50th Anniversary Perspective: Conducting/Semiconducting Conjugated Polymers. A Personal Perspective on the Past and the Future

TM Swager - Macromolecules, 2017 - ACS Publications
It has been about 40 years since the field of organic conducting polymers was ignited by the
demonstration of metallic conductivity in polyacetylene. A retrospective view of this research …

Electronic conductivity, ferrimagnetic ordering, and reductive insertion mediated by organic mixed-valence in a ferric semiquinoid metal–organic framework

LE Darago, ML Aubrey, CJ Yu… - Journal of the …, 2015 - ACS Publications
A three-dimensional network solid composed of FeIII centers and paramagnetic semiquinoid
linkers,(NBu4) 2FeIII2 (dhbq) 3 (dhbq2–/3–= 2, 5-dioxidobenzoquinone/1, 2-dioxido-4, 5 …

Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Evolution of the electronic structure in open-shell donor-acceptor organic semiconductors

Z Chen, W Li, MA Sabuj, Y Li, W Zhu, M Zeng… - Nature …, 2021 - nature.com
Most organic semiconductors have closed-shell electronic structures, however, studies have
revealed open-shell character emanating from design paradigms such as narrowing the …

Octacyanidometallates for multifunctional molecule-based materials

S Chorazy, JJ Zakrzewski, M Magott… - Chemical Society …, 2020 - pubs.rsc.org
Octacyanidometallates have been successfully employed in the design of heterometallic
coordination systems offering a spectacular range of desired physical properties with great …

An overview of molecular layer deposition for organic and organic–inorganic hybrid materials: mechanisms, growth characteristics, and promising applications

X Meng - Journal of Materials Chemistry A, 2017 - pubs.rsc.org
It has been a strong desire for researchers to control material growth at the molecular and
atomic levels. Molecular and atomic layer deposition (MLD and ALD) are two such …

Polymers for electronics and spintronics

P Bujak, I Kulszewicz-Bajer, M Zagorska… - Chemical Society …, 2013 - pubs.rsc.org
This critical review is devoted to semiconducting and high spin polymers which are of great
scientific interest in view of further development of the organic electronics and the emerging …

Recent advances in the design of magnetic molecules for use as cryogenic magnetic coolants

JL Liu, YC Chen, FS Guo, ML Tong - Coordination Chemistry Reviews, 2014 - Elsevier
This review outlines recent advances in the design of 3d-, 4f-, and 3d–4f type magnetic
molecules for use as excellent cryogenic magnetic coolants based on the magnetocaloric …