Photocatalytic late-stage C–H functionalization
The emergence of modern photocatalysis, characterized by mildness and selectivity, has
significantly spurred innovative late-stage C–H functionalization approaches that make use …
significantly spurred innovative late-stage C–H functionalization approaches that make use …
Applications of halogen-atom transfer (XAT) for the generation of carbon radicals in synthetic photochemistry and photocatalysis
The halogen-atom transfer (XAT) is one of the most important and applied processes for the
generation of carbon radicals in synthetic chemistry. In this review, we summarize and …
generation of carbon radicals in synthetic chemistry. In this review, we summarize and …
Late-stage C–H functionalization of azines
CM Josephitis, HMH Nguyen, A McNally - Chemical reviews, 2023 - ACS Publications
Azines, such as pyridines, quinolines, pyrimidines, and pyridazines, are widespread
components of pharmaceuticals. Their occurrence derives from a suite of physiochemical …
components of pharmaceuticals. Their occurrence derives from a suite of physiochemical …
N-Functionalized Pyridinium Salts: A New Chapter for Site-Selective Pyridine C–H Functionalization via Radical-Based Processes under Visible Light Irradiation
Conspectus The radical-mediated C–H functionalization of pyridines has attracted
considerable attention as a powerful tool in synthetic chemistry for the direct …
considerable attention as a powerful tool in synthetic chemistry for the direct …
Energy-transfer-induced [3+ 2] cycloadditions of N–N pyridinium ylides
Photocycloaddition is a powerful reaction to enable the conversion of alkenes into high-
value synthetic materials that are normally difficult to obtain under thermal conditions …
value synthetic materials that are normally difficult to obtain under thermal conditions …
A general electron donor–acceptor complex for photoactivation of arenes via thianthrenation
K Sun, A Shi, Y Liu, X Chen, P **ang, X Wang, L Qu… - Chemical …, 2022 - pubs.rsc.org
General photoactivation of electron donor–acceptor (EDA) complexes between
arylsulfonium salts and 1, 4-diazabicyclo [2.2. 2] octane with visible light or natural sunlight …
arylsulfonium salts and 1, 4-diazabicyclo [2.2. 2] octane with visible light or natural sunlight …
C–H Functionalization of Pyridines via Oxazino Pyridine Intermediates: Switching to para-Selectivity under Acidic Conditions
para-Selective C–H functionalization of pyridines holds a significant value but remains
underdeveloped. Site-switchable C–H functionalization of pyridines under easily tunable …
underdeveloped. Site-switchable C–H functionalization of pyridines under easily tunable …
Site-selective direct C–H pyridylation of unactivated alkanes by triplet excited anthraquinone
Site-selective C–H functionalization in chemical feedstocks is a challenging and useful
reaction in the broad field of chemical research. Here, we report a modular photochemical …
reaction in the broad field of chemical research. Here, we report a modular photochemical …
Electrophotocatalytic Si–H activation governed by polarity-matching effects
Y Jiang, K Xu, C Zeng - CCS Chemistry, 2022 - chinesechemsoc.org
Trialkylsilanes are important building blocks in organic synthesis; however, their widespread
use in redox chemistry is limited by their high oxidation potentials and comparably high …
use in redox chemistry is limited by their high oxidation potentials and comparably high …
Progress in Photoinduced Radical Reactions using Electron Donor‐Acceptor Complexes
L Zheng, L Cai, K Tao, Z **e, YL Lai… - Asian Journal of …, 2021 - Wiley Online Library
Photocatalyzed organic synthesis transformation is a remarkable green synthetic strategy
because of the advantages of operational simplicity, high chemoselectivities, cheap, and …
because of the advantages of operational simplicity, high chemoselectivities, cheap, and …