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From molecular constraints to macroscopic dynamics in associative networks formed by ionizable polymers: A neutron spin echo and molecular dynamics simulations …
The association of ionizable polymers strongly affects their motion in solutions, where the
constraints arising from clustering of the ionizable groups alter the macroscopic dynamics …
constraints arising from clustering of the ionizable groups alter the macroscopic dynamics …
Structure and Dynamics of THF Swollen Polystyrene Ionomer Melts
The structure of ionomers is often trapped in far-from-equilibrium states as a result of
clustering of the ionizable groups. Solvent tweaking of the ionic clusters to allow …
clustering of the ionizable groups. Solvent tweaking of the ionic clusters to allow …
Clustering effects on the structure of ionomer solutions: A combined SANS and simulations study
Ionic assemblies, or clusters, determine the structure and dynamics of ionizable polymers
and enable their many applications. Fundamental to attaining well-defined materials is …
and enable their many applications. Fundamental to attaining well-defined materials is …
Molecular Insight into the Effects of Clustering on the Dynamics of Ionomers in Solutions
Ionizable groups tethered to polymers enable their many current and potential applications.
However, these functionalities drive the formation of physical networks through clustering of …
However, these functionalities drive the formation of physical networks through clustering of …
Response of Sulfonated Polystyrene Melts to Nonlinear Elongation Flows
Ionizable polymers form dynamic networks with domains controlled by two distinct energy
scales, ionic interactions and van der Waals forces; both evolve under elongational flows …
scales, ionic interactions and van der Waals forces; both evolve under elongational flows …
[HTML][HTML] Bead–Spring Simulation of Ionomer Melts—Studying the Effects of Chain-Length and Associating Group Fraction on Equilibrium Structure and Extensional …
Ionomers are associative polymers with diverse applications ranging from selective
membranes and high-performance adhesives to abrasion-and chemical-resistant coatings …
membranes and high-performance adhesives to abrasion-and chemical-resistant coatings …
[HTML][HTML] Structure and Diffusion of Ionic PDMS Melts
Ionic polymers exhibit mechanical properties that can be widely tuned upon selectively
charging them. However, the correlated structural and dynamical properties underlying the …
charging them. However, the correlated structural and dynamical properties underlying the …
Unveiling the transition of tumbling and tank-treading dynamics of star-shaped polyelectrolytes in shear flow by modulating the solution's dielectric properties
B Peng, L Liu, D Wang - The Journal of Chemical Physics, 2024 - pubs.aip.org
The effects of the solution's dielectric properties on the conformation and dynamics of star-
shaped polyelectrolytes in shear flow are investigated using a hybrid simulation method …
shaped polyelectrolytes in shear flow are investigated using a hybrid simulation method …
[HTML][HTML] Construction of ion bonds in gel-free polydiene-based ionomers without compromising molecular weight
S Yue, J Geng, X Zhao, J Hua - Polymer Testing, 2022 - Elsevier
Rubber-based ionomers have attracted extensive research interest from academy and
industry attributing to their distinct physical mechanical properties. However, currently …
industry attributing to their distinct physical mechanical properties. However, currently …
[PDF][PDF] Structure and Diffusion of Ionic PDMS Melts. Polymers 2022, 14, 3070
AV Karatrantos, J Khantaveramongkol, M Kröger - 2022 - researchgate.net
Ionic polymers exhibit mechanical properties that can be widely tuned upon selectively
charging them. However, the correlated structural and dynamical properties underlying the …
charging them. However, the correlated structural and dynamical properties underlying the …