Surface-initiated controlled radical polymerization: state-of-the-art, opportunities, and challenges in surface and interface engineering with polymer brushes

JO Zoppe, NC Ataman, P Mocny, J Wang… - Chemical …, 2017 - ACS Publications
The generation of polymer brushes by surface-initiated controlled radical polymerization (SI-
CRP) techniques has become a powerful approach to tailor the chemical and physical …

Thermoresponsive interfaces obtained using poly (N-isopropylacrylamide)-based copolymer for bioseparation and tissue engineering applications

K Nagase - Advances in Colloid and Interface Science, 2021 - Elsevier
Abstract Poly (N-isopropylacrylamide)(PNIPAAm) is the most well-known and widely used
stimuli-responsive polymer in the biomedical field owing to its ability to undergo temperature …

Creation of softmaterials based on self-oscillating polymer gels

R Yoshida - Polymer Journal, 2022 - nature.com
In 1996, the author reported “self-oscillating” polymer gels that spontaneously repeat
swelling–deswelling changes in a closed solution without any on–off switching by external …

Thermoresponsive polymer assemblies: from molecular design to theranostics application

SL Qiao, M Mamuti, HW An, H Wang - Progress in Polymer Science, 2022 - Elsevier
Molecule self-assembly is a ubiquitous phenomenon and a key driving force for constructing
nanostructures with diverse morphology and controllable size. Recently, interests in …

Recent developments in self-oscillating polymeric systems as smart materials: from polymers to bulk hydrogels

YS Kim, R Tamate, AM Akimoto, R Yoshida - Materials Horizons, 2017 - pubs.rsc.org
As novel functional materials, we developed self-oscillating polymeric materials composed
of synthetic polymers coupled with an oscillating chemical reaction, the so-called Belousov …

[HTML][HTML] Thermoresponsive bio-affinity interfaces for temperature-modulated selective capture and release of targeted exosomes

K Nagase, K Yamazaki, Y Maekawa, H Kanazawa - Materials Today Bio, 2023 - Elsevier
The existing methods for exosome isolation, such as ultracentrifugation, size exclusion, and
affinity separation, suffer from some limitations. Herein, we aimed to develop temperature …

Hydration and dehydration behaviors of poly (N-isopropylacrylamide)-grafted silica beads

K Nagase, J Matsuda, A Takeuchi, Y Ikemoto - Surfaces and Interfaces, 2023 - Elsevier
The use of poly (N-isopropyl acrylamide)(PNIPAAm) in thermoresponsive interfaces for
biomedical applications has been extensively investigated. Understanding the hydration …

Design of functional soft interfaces with precise control of the polymer architecture

T Masuda - Polymer Journal, 2024 - nature.com
Soft interfaces formed by polymer materials are important interfaces for biological systems
(biointerfaces), and controlling their chemical and physical structures at the nanoscale plays …

Thermoresponsive block copolymer brush for temperature-modulated hepatocyte separation

K Nagase, N Kojima, M Goto, T Akaike… - Journal of Materials …, 2022 - pubs.rsc.org
Hepatic tissue engineering may be an effective approach for the treatment of liver disease;
however, its practical application requires hepatic cell separation technologies that do not …

Poly (N-isopropylacrylamide) based thermoresponsive polymer brushes for bioseparation, cellular tissue fabrication, and nano actuators

K Nagase, T Okano, H Kanazawa - Nano-Structures & Nano-Objects, 2018 - Elsevier
Many thermoresponsive surfaces for biomedical applications have been developed using
various techniques for modifying substrates with thermoresponsive polymers. In addition …