Oxide–and silicate–water interfaces and their roles in technology and the environment

JL Bañuelos, E Borguet, GE Brown Jr… - Chemical …, 2023 - ACS Publications
Interfacial reactions drive all elemental cycling on Earth and play pivotal roles in human
activities such as agriculture, water purification, energy production and storage …

Probing the mineral–water interface with nonlinear optical spectroscopy

EHG Backus, J Schaefer, M Bonn - … Chemie International Edition, 2021 - Wiley Online Library
The interaction between minerals and water is manifold and complex: the mineral surface
can be (de) protonated by water, thereby changing its charge; mineral ions dissolved into …

Strong surface hydration and salt resistant mechanism of a new nonfouling zwitterionic polymer based on protein stabilizer TMAO

H Huang, C Zhang, R Crisci, T Lu… - Journal of the …, 2021 - ACS Publications
Zwitterionic polymers exhibit excellent nonfouling performance due to their strong surface
hydrations. However, salt molecules may severely reduce the surface hydrations of typical …

Elucidation of the pH-dependent electric double layer structure at the silica/water interface using heterodyne-detected vibrational sum frequency generation …

F Wei, S Urashima, S Nihonyanagi… - Journal of the American …, 2023 - ACS Publications
The silica/water interface is one of the most abundant charged interfaces in natural
environments, and the elucidation of the water structure at the silica/water interface is …

Variable-angle surface spectroscopy reveals the water structure in the stern layer at charged aqueous interfaces

MM Uddin, MS Azam, DK Hore - Journal of the American …, 2024 - ACS Publications
At charged aqueous interfaces, the second-order nonlinear optical response originates from
water molecules within the diffuse part of the electrical double layer, which are ordered by …

Correlation between electrostatic and hydration forces on silica and gibbsite surfaces: An atomic force microscopy study

A Klaassen, F Liu, F Mugele, I Siretanu - Langmuir, 2022 - ACS Publications
The balance between hydration and Derjaguin–Landau–Verwey–Overbeek (DLVO) forces
at solid–liquid interfaces controls many processes, such as colloidal stability, wetting …

Role of ions on the surface-bound water structure at the silica/water interface: Identifying the spectral signature of stability

B Rehl, JM Gibbs - The Journal of Physical Chemistry Letters, 2021 - ACS Publications
Isolating the hydrogen-bonding structure of water immediately at the surface is challenging,
even with surface-specific techniques like sum-frequency generation (SFG), because of the …

Ordered water layer on the macroscopically hydrophobic fluorinated polymer surface and its ultrafast vibrational dynamics

J Zhang, J Tan, R Pei, S Ye, Y Luo - Journal of the American …, 2021 - ACS Publications
Hydrophobic-like water monolayers have been predicted at the metal and some polar
surfaces by theoretical simulations. However, direct experimental evidence for the presence …

Molecular fingerprints of hydrophobicity at aqueous interfaces from theory and vibrational spectroscopies

S Pezzotti, A Serva, F Sebastiani… - The Journal of …, 2021 - ACS Publications
Hydrophobicity/hydrophilicity of aqueous interfaces at the molecular level results from a
subtle balance in the water–water and water–surface interactions. This is characterized here …