The preparation of well-defined functionalized polyolefins via coordination-insertion
polymerization method is a hot topic in polymer science. Late transition organometallic …

Studies on transition-metal catalyzed olefin-polar monomer coordination copolymerization
and their resulting polar-functionalized polyolefin materials have attracted attention from …

The practical synthesis of polar‐functionalized polyolefins using transition‐metal‐catalyzed
copolymerization of olefins with polar monomers is a challenge; the use of heterogeneous …

In this contribution, we install an azobenzene functionality in olefin polymerization catalysts
and use light to modulate their properties via photoinduced trans–cis isomerization of the …

Transition metal-catalyzed olefin polymerization dominates in the polyolefin field, and we
still have limited control over a catalyst's behavior. In addition to traditional steric and …

Synthetic polymer chemistry endeavors to imitate the spatial and temporal control exhibited
within biological systems to obtain well-defined polymeric materials with unique structures …

Nickel‐and palladium‐catalyzed insertion copolymerization of ethylene and acrylate
comonomers for synthesis of ethylene‐acrylates copolymers have attracted much academic …

The transition-metal-catalyzed copolymerization of olefins with polar comonomers is a direct
strategy to access polar-functionalized polyolefins in an economical manner. Due to the …

Metal–metal cooperativity effects have been extensively explored in olefin polymerization,
along with the design and preparation of many binuclear transition metal catalysts. However …

Polar monomer-induced β-H elimination is a key elementary step in polar polyolefin
synthesis by coordination polymerization but remains underexplored. Herein, we show that …