The fleeting lifetimes of reactive intermediates in C–H functionalization chemistry often
prevent their direct characterization. For example, the critical nitrenoid intermediates that …

The past few decades have witnessed extensive efforts to disclose the unique reactivity of
metal–nitrenes, because they could be a powerful synthetic tool for introducing the amine …

Although intense research over the last 2 decades revealed a diverse proficiency of nitrene
species in chemistry disciplines, control of the selectivity in the reaction manifold has …

Theoretical calculations have been performed to gain deeper understanding on the
mechanism of Cp* Co (III)-catalysed C (sp3)–H amination of 8-methylquinoline with phenyl …

The stereoselective, rhodium‐catalysed aziridination of styrene derivatives with a chiral N‐
mesyloxycarbamate was found to be highly substrate dependent. A density functional theory …

The mechanism, chemo-and regioselectivity of Mn-catalyzed intermolecular CH amination of
internal olefin have been studied using B3LYP functional. The internal allylic CH amination …

Possible mechanisms and the selectivity of Z-and E-substrates for the Csp3–H amination
catalyzed by the metal phthalocyanines have been explored by DFT calculations. Here the …

Discrete Fourier transform (DFT) analyses of structure, stability, and reactivity of the
(tetracarboxylate)‐[M 2] complexes of late transition metals with d 7, d 8, and d 9 electron …

Computational studies on Ir (III)-catalyzed intermolecular branch-selective allylic C–H
amination of terminal olefins with methyl dioxazolone have been carried out to investigate …

A review of photocatalytic strategies, involving radical intermediates of importance in organic
synthesis, has appeared. The fact that photocatalytic cycles are composed of three steps …