Electro-optical π-radicals: design advances, applications and future perspectives

P Murto, H Bronstein - Journal of Materials Chemistry C, 2022 - pubs.rsc.org
The unique open-shell electronic structure of neutral π-radicals has inspired research on
novel molecular materials for over a century. In recent years, rapid development in carbon …

Research progress on triarylmethyl radical-based high-efficiency OLED

J Luo, XF Rong, YY Ye, WZ Li, XQ Wang, W Wang - Molecules, 2022 - mdpi.com
Perchlorotrityl radical (PTM), tris (2, 4, 6-trichlorophenyl) methyl radical (TTM),(3, 5-dichloro-
4-pyridyl) bis (2, 4, 6 trichlorophenyl) methyl radical (PyBTM),(N-carbazolyl) bis (2, 4, 6 …

Towards efficient and stable donor‐acceptor luminescent radicals

C Lu, E Cho, Z Cui, Y Gao, W Cao… - Advanced …, 2023 - Wiley Online Library
In contrast to closed‐shell luminescent molecules, the electronic ground state and lowest
excited state in organic luminescent radicals are both spin doublet, which results in spin …

Achieving Nearly 100% Photoluminescence Quantum Efficiency in Organic Radical Emitters by Fine‐Tuning the Effective Donor‐Acceptor Distance

C Lu, E Cho, K Wan, C Wu, Y Gao… - Advanced Functional …, 2024 - Wiley Online Library
Abstract Donor‐acceptor (D–A•) type luminescent organic radicals have received
widespread attention as efficient doublet emitters. However, their generally low …

Neutral Stable Nitrogen‐Centered Radicals: Structure, Properties, and Recent Functional Application Progress

S Gao, F Li - Advanced Functional Materials, 2023 - Wiley Online Library
Persistent and stable nitrogen‐centered organic radicals, including non‐heterocyclic/
heterocyclic nitrogen‐centered radicals and nitrogen‐centered radical complexes, have …

2,7‐Substituted N‐Carbazole Donors on Tris(2,4,6‐trichlorophenyl)methyl Radicals with High Quantum Yield

L Chen, M Arnold, Y Kittel, R Blinder… - Advanced Optical …, 2022 - Wiley Online Library
Doublet spin properties of organic open‐shell luminophores evade the formation of dark
triplet states, thus making radicals favorable emitters for next generation organic light …

Organic luminescent radical-based film probes with reversible doublet state switching for ultrasensitive nerve agents simulant vapor detection

Y Zhang, A Abdurahman, P Zheng, H Mu, F Li… - Sensors and Actuators B …, 2023 - Elsevier
Donor-acceptor (DA) type organic luminescent materials with intramolecular charge transfer
(ICT) mechanism constitute a significant class of fluorescent probes for nerve agents …

Organic radical emitters: nature of doublet excitons in emissive layers

H Abroshan, P Winget, HS Kwak, CT Brown… - Physical Chemistry …, 2022 - pubs.rsc.org
Organic radical emitters have received significant attention as a new route to efficient
organic light-emitting diodes (OLEDs). The electronic structure of radical emitters allows …

An energetics assessment of benzo [a] tetracene and benzo [a] pyrene as triplet–triplet annihilation emitters

X Wang, N Marom - Molecular Systems Design & Engineering, 2022 - pubs.rsc.org
Optical upconversion (UC) of low energy photons into high energy photons enables solar
cells to harvest photons with energies below the band gap of the absorber, reducing the …

Highly Efficient Near‐Infrared Luminescent Radicals with Emission Peaks over 750 nm

C Wu, C Lu, S Yu, M Zhang, H Zhang… - Angewandte Chemie …, 2024 - Wiley Online Library
Purely organic molecules exhibiting near‐infrared (NIR) emission possess considerable
potential for applications in both biological and optoelectronic technological domains, owing …