Photoactive copper complexes: properties and applications

J Beaudelot, S Oger, S Perusko, TA Phan… - Chemical …, 2022 - ACS Publications
Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …

TADF Material Design: Photophysical Background and Case Studies Focusing on Cu(I) and Ag(I) Complexesa

H Yersin, R Czerwieniec, MZ Shafikov… - … : Materials Based on …, 2018 - Wiley Online Library
Designing of thermally activated delayed fluorescence (TADF) compounds with short TADF
decay time and high emission quantum yield is a challenge. This chapter introduces …

Photoredox catalysts based on earth-abundant metal complexes

BM Hockin, C Li, N Robertson… - Catalysis Science & …, 2019 - pubs.rsc.org
Over the last decade, visible light photoredox catalysis has exploded into the consciousness
of the synthetic chemist. The principal photocatalysts used are based on rare and toxic …

Facile oxidative addition of aryl iodides to gold (I) by ligand design: bending turns on reactivity

M Joost, A Zeineddine, L Estevez… - Journal of the …, 2014 - ACS Publications
Thanks to rational ligand design, the first gold (I) complexes to undergo oxidative addition of
aryl iodides were discovered. The reaction proceeds under mild conditions and is general …

Cu (I) and Ag (I) complexes with a new type of rigid tridentate N, P, P-ligand for thermally activated delayed fluorescence and OLEDs with high external quantum …

M Klein, N Rau, M Wende, J Sundermeyer… - Chemistry of …, 2020 - ACS Publications
Neutral Cu (I) and Ag (I) complexes with a new rigid tridentate N, P, P ligand (dmpzpp, 3, 5-
dimethyl-1-(2-((2-(di-o-tolyl) phosphanyl)(o-tolyl)-phosphanyl) phenyl)-1 H-pyrazole), giving …

Thermally activated delayed fluorescence from Ag (I) complexes: a route to 100% quantum yield at unprecedentedly short decay time

MZ Shafikov, AF Suleymanova, R Czerwieniec… - Inorganic …, 2017 - ACS Publications
The four new Ag (I) complexes Ag (phen)(P2-nCB)(1), Ag (idmp)(P2-nCB)(2), Ag (dmp)(P2-
nCB)(3), and Ag (dbp)(P2-nCB)(4) with P2-nCB= bis (diphenylphosphine)-nido-carborane …

Design strategy for Ag (I)-based thermally activated delayed fluorescence reaching an efficiency breakthrough

MZ Shafikov, AF Suleymanova… - Chemistry of …, 2017 - ACS Publications
A design strategy for the development of Ag (I)-based materials for thermally activated
delayed fluorescence (TADF) is presented. Although Ag (I) complexes usually do not show …

Wide-bite-angle diphosphine ligands in thermally activated delayed fluorescent copper (I) complexes: impact on the performance of electroluminescence applications

C Li, CFR Mackenzie, SA Said, AK Pal… - Inorganic …, 2021 - ACS Publications
We report a series of seven cationic heteroleptic copper (I) complexes of the form [Cu (P^
P)(dmphen)] BF4, where dmphen is 2, 9-dimethyl-1, 10-phenanthroline and P^ P is a …

Heteroleptic copper (I) pseudorotaxanes incorporating macrocyclic phenanthroline ligands of different sizes

M Mohankumar, M Holler, E Meichsner… - Journal of the …, 2018 - ACS Publications
A series of copper (I) pseudorotaxanes has been prepared from bis [2-(diphenylphosphino)
phenyl] ether (POP) and macrocyclic phenanthroline ligands with different ring sizes (m30 …

Origin of a counterintuitive yellow light-emitting electrochemical cell based on a blue-emitting heteroleptic copper (I) complex

MD Weber, C Garino, G Volpi, E Casamassa… - Dalton …, 2016 - pubs.rsc.org
This work provides the synthesis, structural characterization, electrochemical and
photophysical features, as well as the application in light-emitting electrochemical cells …