Diversifying Cross‐Coupling Strategies, Catalysts and Monomers for the Controlled Synthesis of Conjugated Polymers

MA Baker, CH Tsai, KJT Noonan - Chemistry–A European …, 2018 - Wiley Online Library
Chain‐growth polymerization of aromatic building blocks (termed catalyst‐transfer
polycondensation or CTP) has emerged as a powerful method for the controlled synthesis of …

[HTML][HTML] The influence of physicochemical properties on the processibility of conducting polymers: A bioelectronics perspective

J Heck, J Goding, RP Lara, R Green - Acta Biomaterialia, 2022 - Elsevier
Conducting polymers (CPs) possess unique electrical and electrochemical properties and
hold great potential for different applications in the field of bioelectronics. However, the …

Controlling Molecular Weight of a High Efficiency Donor‐Acceptor Conjugated Polymer and Understanding Its Significant Impact on Photovoltaic Properties

W Li, L Yang, JR Tumbleston, L Yan, H Ade… - Advanced …, 2014 - Wiley Online Library
DOI: 10.1002/adma. 201305251 molecular weight centered on 40 kg/mol (calculated Mn). A
careful study of a set of PBnDT-FTAZ with precisely controlled molecular weight (from 10 …

The history of palladium-catalyzed cross-couplings should inspire the future of catalyst-transfer polymerization

AK Leone, EA Mueller, AJ McNeil - Journal of the American …, 2018 - ACS Publications
Conjugated polymers are the workhorse materials in organic electronics, a field that is
rapidly growing to encompass energy storage devices such as supercapacitors and …

Review of waterborne organic semiconductor colloids for photovoltaics

A Holmes, E Deniau, C Lartigau-Dagron, A Bousquet… - ACS …, 2021 - ACS Publications
Development of carbon neutral and sustainable energy sources should be considered as a
top priority solution for the growing worldwide energy demand. Photovoltaics are a strong …

Nickel-catalyzed suzuki polycondensation for controlled synthesis of ester-functionalized conjugated polymers

Y Qiu, JC Worch, A Fortney, C Gayathri, RR Gil… - …, 2016 - ACS Publications
Controlled synthesis of conjugated polymers with functional side chains is of great
importance, affording well-defined optoelectronic materials possessing enhanced stability …

Catalyst-dependent intrinsic ring-walking behavior on π-face of conjugated polymers

K Mikami, M Nojima, Y Masumoto, Y Mizukoshi… - Polymer …, 2017 - pubs.rsc.org
We show that ring-walking behavior on the π-face of conjugated polymers is catalyst-
dependent, and this significantly affects the composition of the products in catalyst-transfer …

Preparation of an Aurylated Alkylthiophene Monomer via C–H Activation for Use in Pd-PEPPSI-iPr Catalyzed-Controlled Chain Growth Polymerization

SL Suraru, JA Lee, CK Luscombe - ACS Macro Letters, 2016 - ACS Publications
In the search for new synthetic routes toward greener and more facile syntheses of
conjugated polymers, C–H functionalization provides a promising solution by minimizing the …

Exploring the mechanism of Grignard metathesis polymerization of 3-alkylthiophenes

N Bahri-Laleh, A Poater, L Cavallo… - Dalton …, 2014 - pubs.rsc.org
In this study we have investigated computationally the mechanism of polymerization of 2, 5-
dibromo 3-butylthiophene via the GRIM method, with the focus on the origin of the head to …

Two-dimensional polythiophene homopolymer as promising hole transport material for high-performance perovskite solar cells

HC Hsieh, CY Hsiow, YA Su, YC Liu, W Chen… - Journal of Power …, 2019 - Elsevier
A polythiophene homopolymer with conjugated side chains (2D-PT) was applied as a hole
transport material (HTM) of perovskite solar cells (PSCs). The all-conjugated two …