Recent advances in tetra-(Ti, Sn, Zr, Hf) and pentavalent (Nb, V, Ta) metal-substituted molecular sieve catalysis

SL Suib, J Přech, E Szaniawska, J Čejka - Chemical Reviews, 2022 - ACS Publications
Metal substitution of molecular sieve systems is a major driving force in develo** novel
catalytic processes to meet current demands of green chemistry concepts and to achieve …

Emerging heterogeneous catalysts for biomass conversion: studies of the reaction mechanism

L Lin, X Han, B Han, S Yang - Chemical Society Reviews, 2021 - pubs.rsc.org
The development of efficient catalysts to break down and convert woody biomass will be a
paradigm shift in delivering the global target of sustainable economy and environment via …

Zeolite-encapsulated Pt nanoparticles for tandem catalysis

HJ Cho, D Kim, J Li, D Su, B Xu - Journal of the American …, 2018 - ACS Publications
Encapsulation of metal nanoparticles in a zeolite matrix is a promising route to integrate
multiple sequential reactions into a one-pot and one-step tandem catalytic reaction. We …

Titration and quantification of open and closed Lewis acid sites in Sn-Beta zeolites that catalyze glucose isomerization

JW Harris, MJ Cordon, JR Di Iorio, JC Vega-Vila… - Journal of …, 2016 - Elsevier
Methods to quantify framework Lewis acidic Sn 4+ sites in zeolite Beta (Sn-Beta) with four
Lewis base titrants (pyridine, deuterated acetonitrile, n-propylamine, ammonia) were …

Lewis acid zeolites for biomass conversion: Perspectives and challenges on reactivity, synthesis, and stability

HY Luo, JD Lewis… - Annual review of chemical …, 2016 - annualreviews.org
Zeolites containing Sn, Ti, Zr, Hf, Nb, or Ta heteroatoms are versatile catalysts for the
activation and conversion of oxygenated molecules owing to the unique Lewis acid …

Spectroscopic signature of Lewis acidic framework and extraframework Sn sites in beta zeolites

W Dai, Q Lei, G Wu, N Guan, M Hunger, L Li - ACS Catalysis, 2020 - ACS Publications
A variety of Sn-containing Beta zeolites possessing framework or extraframework Sn sites
were prepared by a two-step postsynthesis procedure. The nature of these Sn species was …

Insight into tri-coordinated aluminum dependent catalytic properties of dealuminated Y zeolites in oxidative desulfurization

Z Zhu, H Ma, W Liao, P Tang, K Yang, T Su… - Applied Catalysis B …, 2021 - Elsevier
Aluminosilicate zeolite as a versatile material is of great importance for industrial catalysis,
whose noumenal Brønsted and Lewis acid sites generally determine the activity, selectivity …

Synthesis and Catalytic Applications of Advanced Sn‐and Zr‐Zeolites Materials

X Liu, Z Zhu - Advanced Science, 2024 - Wiley Online Library
The incorporation of isolated Sn (IV) and Zr (IV) ions into silica frameworks is attracting
widespread attention, which exhibits remarkable catalytic performance (conversion …

Heteroatom Lewis acid zeolites: synthesis, characterization and application in the conversion of biomass-derived oxygenates

Z Yang, Q Ge, X Zhu - Green Chemistry, 2024 - pubs.rsc.org
Heteroatom (such as Ti, Sn, Zr, Hf and others) Lewis acid zeolites contain Lewis acid site
(LAS) centers with tetrahedral coordination confined in micropores of zeolites with varied …

Lewis acid catalysis on single site Sn centers incorporated into silica hosts

P Ferrini, J Dijkmans, R De Clercq… - Coordination Chemistry …, 2017 - Elsevier
Tetrahedral Sn built into microporous silica frameworks such as zeolites and structured
mesoporous silica can be used as heterogeneous Lewis acid catalysts. These materials …