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Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?
F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …
with focus on how they contribute to the improvement of selectivity in heterogeneous …
Dilute alloys based on Au, Ag, or Cu for efficient catalysis: from synthesis to active sites
The development of new catalyst materials for energy-efficient chemical synthesis is critical
as over 80% of industrial processes rely on catalysts, with many of the most energy-intensive …
as over 80% of industrial processes rely on catalysts, with many of the most energy-intensive …
Guidelines to achieving high selectivity for the hydrogenation of α, β-unsaturated aldehydes with bimetallic and dilute alloy catalysts: a review
Selective hydrogenation of α, β-unsaturated aldehydes to unsaturated alcohols is a
challenging class of reactions, yielding valuable intermediates for the production of …
challenging class of reactions, yielding valuable intermediates for the production of …
Directing reaction pathways via in situ control of active site geometries in PdAu single-atom alloy catalysts
The atomic scale structure of the active sites in heterogeneous catalysts is central to their
reactivity and selectivity. Therefore, understanding active site stability and evolution under …
reactivity and selectivity. Therefore, understanding active site stability and evolution under …
Tuning the electronic structure of Ag-Pd alloys to enhance performance for alkaline oxygen reduction
Alloying is a powerful tool that can improve the electrocatalytic performance and viability of
diverse electrochemical renewable energy technologies. Herein, we enhance the activity of …
diverse electrochemical renewable energy technologies. Herein, we enhance the activity of …
Operando insights into nanoparticle transformations during catalysis
Nanostructured materials play an important role in today's chemical industry, acting as
catalysts in heterogeneous thermal and electrocatalytic processes for chemical energy …
catalysts in heterogeneous thermal and electrocatalytic processes for chemical energy …
Decoding reactive structures in dilute alloy catalysts
Rational catalyst design is crucial toward achieving more energy-efficient and sustainable
catalytic processes. Understanding and modeling catalytic reaction pathways and kinetics …
catalytic processes. Understanding and modeling catalytic reaction pathways and kinetics …
Dynamical study of adsorbate-induced restructuring kinetics in bimetallic catalysts using the PdAu (111) model system
Dynamic restructuring of bimetallic catalysts plays a crucial role in their catalytic activity and
selectivity. In particular, catalyst pretreatment with species such as carbon monoxide and …
selectivity. In particular, catalyst pretreatment with species such as carbon monoxide and …
Studying, promoting, exploiting, and predicting catalyst dynamics: the next frontier in heterogeneous catalysis
Develo** heterogeneous catalysts involves continuous efforts in understanding and
designing active sites with improved performance for various applications. In recent years …
designing active sites with improved performance for various applications. In recent years …
Moderate Surface Segregation Promotes Selective Ethanol Production in CO2 Hydrogenation Reaction over CoCu Catalysts
Cobalt‐copper (CoCu) catalysts have industrial potential in CO/CO2 hydrogenation
reactions, and CoCu alloy has been elucidated as a major active phase during reactions …
reactions, and CoCu alloy has been elucidated as a major active phase during reactions …