Polymer synthesis and processing using supercritical carbon dioxide
AI Cooper - Journal of Materials Chemistry, 2000 - pubs.rsc.org
Carbon dioxide is a clean and versatile solvent for the synthesis and processing of a range
of materials. This review focuses on recent advances in polymer synthesis and processing …
of materials. This review focuses on recent advances in polymer synthesis and processing …
CO2 Technology Platform: An Important Tool for Environmental Problem Solving
SL Wells, J DeSimone - Angewandte Chemie International …, 2001 - Wiley Online Library
CO2 is a good solvent for many substances when compressed into its liquid or supercritical
fluid state. Above the critical temperature and critical pressure (Tc= 31° C, Pc= 73.8 bar, see …
fluid state. Above the critical temperature and critical pressure (Tc= 31° C, Pc= 73.8 bar, see …
Effect of surfactants on the interfacial tension and emulsion formation between water and carbon dioxide
The lowering of the interfacial tension (γ) between water and carbon dioxide by various
classes of surfactants is reported and used to interpret complementary measurements of the …
classes of surfactants is reported and used to interpret complementary measurements of the …
Relationship between Graft Density and the Dilute Solution Structure of Bottlebrush Polymers: An Inter-Chemistry Comparison and Scaling Analysis
Bottlebrush polymers are an important class of materials which consist of side chains grafted
along a linear backbone. There has been a significant effort to understand structure …
along a linear backbone. There has been a significant effort to understand structure …
Water-in-CO2 Microemulsions Studied by Small-Angle Neutron Scattering
Aggregate structures in water-in-CO2 microemulsions were studied by high-pressure small-
angle neutron scattering (SANS). With liquid CO2 at 15° C, the partially fluorinated, di-chain …
angle neutron scattering (SANS). With liquid CO2 at 15° C, the partially fluorinated, di-chain …
Structure–Property Relationships in CO2-philic (Co)polymers: Phase Behavior, Self-Assembly, and Stabilization of Water/CO2 Emulsions
This Review provides comprehensive guidelines for the design of CO2-philic copolymers
through an exhaustive and precise coverage of factors governing the solubility of different …
through an exhaustive and precise coverage of factors governing the solubility of different …
Synthesis of TiO2 Nanoparticles Utilizing Hydrated Reverse Micelles in CO2
Titanium dioxide nanoparticles were produced by the controlled hydrolysis of titanium
tetraisopropoxide (TTIP) in the presence of reverse micelles formed in CO2 with the …
tetraisopropoxide (TTIP) in the presence of reverse micelles formed in CO2 with the …
Recent applications of small-angle neutron scattering in strongly interacting soft condensed matter
GD Wignall, YB Melnichenko - Reports on Progress in Physics, 2005 - iopscience.iop.org
Before the application of small-angle neutron scattering (SANS) to the study of polymer
structure, chain conformation studies were limited to light and small-angle x-ray scattering …
structure, chain conformation studies were limited to light and small-angle x-ray scattering …
Dispersion Polymerization in Supercritical CO2 with a Siloxane-Based Macromonomer: 1. The Particle Growth Regime
Particle growth rates were analyzed for the dispersion polymerization of methyl methacrylate
(MMA) in supercritical carbon dioxide at 65° C stabilized with a poly (dimethyl siloxane) …
(MMA) in supercritical carbon dioxide at 65° C stabilized with a poly (dimethyl siloxane) …
Stubby Surfactants for Stabilization of Water and CO2 Emulsions: Trisiloxanes
Amphiphiles of a new class, with very short and bulky CO2-philic headgroups, the trisiloxane
surfactants of the form ((CH3) 3SiO) 2Si (CH3)(CH2) 3EO n R, where EO stands for ethylene …
surfactants of the form ((CH3) 3SiO) 2Si (CH3)(CH2) 3EO n R, where EO stands for ethylene …