Luminescent Complexes of Platinum, Iridium, and Coinage Metals Containing N-Heterocyclic Carbene Ligands: Design, Structural Diversity, and Photophysical …

H Amouri - Chemical Reviews, 2022 - ACS Publications
The employment of N-heterocyclic carbenes (NHCs) to design luminescent metal
compounds has been the focus of recent intense investigations because of the strong σ …

Molecular Design Principles to Elongate the Metal-to-Ligand Charge Transfer Excited-State Lifetimes of Square-Planar Nickel (II) Complexes

T Ogawa, N Sinha, B Pfund, A Prescimone… - Journal of the …, 2022 - ACS Publications
Square-planar NiII complexes and their electronically excited states play key roles in cross-
coupling catalysis and could offer new opportunities to complement well-known …

Nickel (II) Analogues of Phosphorescent Platinum (II) Complexes with Picosecond Excited‐State Decay

T Ogawa, OS Wenger - Angewandte Chemie International …, 2023 - Wiley Online Library
Square‐planar NiII complexes are interesting as cheaper and more sustainable alternatives
to PtII luminophores widely used in lighting and photocatalysis. We investigated the excited …

Group 10 metal-cyanide scaffolds in complexes and extended frameworks: Properties and applications

M Sadeghian, MG Haghighi, E Lalinde… - Coordination Chemistry …, 2022 - Elsevier
To date, group 10 metal-cyanide scaffolds as promising candidates in the form of discrete
organometallic complexes or one-, two-and three-dimensional coordination polymers have …

Ferrous and ferric complexes with cyclometalating N-heterocyclic carbene ligands: a case of dual emission revisited

CE Johnson, J Schwarz, M Deegbey, O Prakash… - Chemical …, 2023 - pubs.rsc.org
Iron N-heterocyclic carbene (FeNHC) complexes with long-lived charge transfer states are
emerging as a promising class of photoactive materials. We have synthesized [FeII (ImP) …

Isomerism, aggregation-induced emission and mechanochromism of isocyanide cycloplatinated (II) complexes

M Martínez-Junquera, R Lara, E Lalinde… - Journal of Materials …, 2020 - pubs.rsc.org
This work describes two series of neutral luminescent cyclometalated Pt (II) complexes
incorporating chloride/isocyanide,[Pt (C^ N) Cl (CNXyl)](1–3), and alkynyl/isocyanide [Pt (C …

Polymorphism and Mechanochromism in 2-Phenylbenzothiazole Cyclometalated PtII Complexes with Chelating NO Ligands

D Gómez de Segura, E Lalinde, MT Moreno - Inorganic Chemistry, 2022 - ACS Publications
New cyclometalated PtII complexes with 2-phenylbenzothiazole (pbt) and two different
picolinate ligands [Pt (pbt)(R-pic-κ N, O)](R= H (1), OH (2)) were prepared. In contrast to 1 …

Pure blue phosphorescent platinum (II) emitters supported by NHC-based pincer type ligands with unitary emission quantum yields

J Liu, TL Lam, MK Sit, Q Wan, C Yang… - Journal of Materials …, 2022 - pubs.rsc.org
A series of phosphorescent Pt (II) complexes containing a bis-N-heterocyclic carbene (NHC)-
pincer-type ligand and a monodentate ancillary ligand,[Pt (CNHC^ CAr^ CNHC) L](where L …

Application of five-membered ring products of cyclometalation reactions as sensing materials in sensing devices

I Omae - Journal of Organometallic Chemistry, 2016 - Elsevier
Some organometallic compounds, especially five-membered ring products of
cyclometalation reactions, can be utilized as sensing materials in sensors for detecting …

Platinum complexes bearing normal and mesoionic N-heterocyclic carbene based pincer ligands: syntheses, structures, and photo-functional attributes

AR Naziruddin, CS Lee, WJ Lin, BJ Sun, KH Chao… - Dalton …, 2016 - pubs.rsc.org
Platinum complexes featuring pyridine bis-N-heterocyclic-imidazol-2-ylidene/-mesoionic-
triazol-5-ylidene donors as pincer ligands and chloro (–Cl), acetonitrile (–NCCH3) or cyano …