Chemically diverse small molecule fluorescent chemosensors for copper ion
The development of sensitive chromogenic chemosensors for sensing Cu 2+ has been
receiving much attention in recent years because of their potential application in clinical …
receiving much attention in recent years because of their potential application in clinical …
Magnetic interactions in molecules and highly correlated materials: physical content, analytical derivation, and rigorous extraction of magnetic Hamiltonians
Magnetism is a phenomenon that has always captured the imagination of humans. Its
discovery in the western world is attributed to the ancient Greek civilization. More than 2500 …
discovery in the western world is attributed to the ancient Greek civilization. More than 2500 …
Organic mixed‐valence compounds: a playground for electrons and holes
A Heckmann, C Lambert - Angewandte Chemie International …, 2012 - Wiley Online Library
Mixed‐valence (MV) compounds are excellent model systems for the investigation of basic
electron‐transfer (ET) or charge‐transfer (CT) phenomena. These issues are important in …
electron‐transfer (ET) or charge‐transfer (CT) phenomena. These issues are important in …
Electronic communication through unsaturated hydrocarbon bridges in homobimetallic organometallic complexes
P Aguirre-Etcheverry, D O'Hare - Chemical reviews, 2010 - ACS Publications
Bimetallic (binuclear metal) complexes contain two metal centers, either linked directly or, as
in the complexes considered in this review, through a bridging ligand. Homometallic …
in the complexes considered in this review, through a bridging ligand. Homometallic …
Quantum-chemical insights into mixed-valence systems: within and beyond the Robin–Day scheme
In mixed-valence (MV) systems essentially identical, more or less electronically coupled,
redox centres are brought into formally different oxidation states by removal or addition of an …
redox centres are brought into formally different oxidation states by removal or addition of an …
Half-Wave Potential Splittings ΔE1/2 as a Measure of Electronic Coupling in Mixed-Valent Systems: Triumphs and Defeats
RF Winter - Organometallics, 2014 - ACS Publications
This review is a cautionary note against the often purported direct relation between the half-
wave potential splitting Δ E 1/2 (or Δ E°) for stepwise, consecutive electron transfer from …
wave potential splitting Δ E 1/2 (or Δ E°) for stepwise, consecutive electron transfer from …
A reliable quantum-chemical protocol for the characterization of organic mixed-valence compounds
M Renz, K Theilacker, C Lambert… - Journal of the American …, 2009 - ACS Publications
Structures, dipole moments, electron-transfer barriers, and spin density distributions of a
series of mixed-valent bistriarylamin radical cations have been studied systematically by …
series of mixed-valent bistriarylamin radical cations have been studied systematically by …
Pyrene molecular orbital shuffle—controlling excited state and redox properties by changing the nature of the frontier orbitals
J Merz, J Fink, A Friedrich… - … A European Journal, 2017 - Wiley Online Library
We show that by judicious choice of substituents at the 2‐and 7‐positions of pyrene, the
frontier orbital order of pyrene can be modified, giving enhanced control over the nature and …
frontier orbital order of pyrene can be modified, giving enhanced control over the nature and …
Isolable bis (triarylamine) dications: analogues of Thiele's, Chichibabin's, and Muller's hydrocarbons
G Tan, X Wang - Accounts of Chemical Research, 2017 - ACS Publications
Conspectus Since the pioneering work by Thiele and Chichibabin, who synthesized the first
diradicals bridged by phenylene and biphenylene groups in 1904 and 1907, respectively …
diradicals bridged by phenylene and biphenylene groups in 1904 and 1907, respectively …