First-generation organic reaction intermediates in zeolite chemistry and catalysis
Zeolite chemistry and catalysis are expected to play a decisive role in the next decade (s) to
build a more decentralized renewable feedstock-dependent sustainable society owing to the …
build a more decentralized renewable feedstock-dependent sustainable society owing to the …
Progress and challenges in nitrous oxide decomposition and valorization
X Wu, J Du, Y Gao, H Wang, C Zhang… - Chemical Society …, 2024 - pubs.rsc.org
Nitrous oxide (N2O) decomposition is increasingly acknowledged as a viable strategy for
mitigating greenhouse gas emissions and addressing ozone depletion, aligning significantly …
mitigating greenhouse gas emissions and addressing ozone depletion, aligning significantly …
Single atom catalysts for selective methane oxidation to oxygenates
Direct conversion of methane (CH4) to C1–2 liquid oxygenates is a captivating approach to
lock carbons in transportable value-added chemicals, while reducing global warming …
lock carbons in transportable value-added chemicals, while reducing global warming …
Activation and conversion of alkanes in the confined space of zeolite-type materials
Microporous zeolite-type materials, with crystalline porous structures formed by well-defined
channels and cages of molecular dimensions, have been widely employed as …
channels and cages of molecular dimensions, have been widely employed as …
Computational approach to molecular catalysis by 3d transition metals: challenges and opportunities
Computational chemistry provides a versatile toolbox for studying mechanistic details of
catalytic reactions and holds promise to deliver practical strategies to enable the rational in …
catalytic reactions and holds promise to deliver practical strategies to enable the rational in …
Reactive high-spin iron (IV)-oxo sites through dioxygen activation in a metal–organic framework
In nature, nonheme iron enzymes use dioxygen to generate high-spin iron (IV)= O species
for a variety of oxygenation reactions. Although synthetic chemists have long sought to …
for a variety of oxygenation reactions. Although synthetic chemists have long sought to …
Interlayer Structure Manipulation of Iron Oxychloride by Potassium Cation Intercalation to Steer H2O2 Activation Pathway
Structural regulation of the active centers is often pivotal in controlling the catalytic functions,
especially in iron-based oxidation systems. Here, we discovered a significantly altered …
especially in iron-based oxidation systems. Here, we discovered a significantly altered …
Beyond radical rebound: methane oxidation to methanol catalyzed by iron species in metal–organic framework nodes
MC Simons, SD Prinslow, M Babucci… - Journal of the …, 2021 - ACS Publications
Recent work has exploited the ability of metal–organic frameworks (MOFs) to isolate Fe sites
that mimic the structures of sites in enzymes that catalyze selective oxidations at low …
that mimic the structures of sites in enzymes that catalyze selective oxidations at low …
Cage effects control the mechanism of methane hydroxylation in zeolites
Catalytic conversion of methane to methanol remains an economically tantalizing but
fundamentally challenging goal. Current technologies based on zeolites deactivate too …
fundamentally challenging goal. Current technologies based on zeolites deactivate too …
Iron-and cobalt-catalyzed C (sp 3)–H bond functionalization reactions and their application in organic synthesis
Y Liu, T You, HX Wang, Z Tang, CY Zhou… - Chemical Society …, 2020 - pubs.rsc.org
Direct C–H bond functionalization catalyzed by non-precious transition metals is an
attractive strategy in synthetic chemistry. Compared with the precious metals rhodium …
attractive strategy in synthetic chemistry. Compared with the precious metals rhodium …