Catalytic hydrogen atom transfer from metal‐hydrides to alkenes allows feedstock olefins to
be used as alkyl radical precursors. The chemoselectivity of this process makes it an …

Electro‐organic synthesis has attracted a lot of attention in pharmaceutical science,
medicinal chemistry, and future industrial applications in energy storage and conversion. To …

Azetidines are prominent structural scaffolds in bioactive molecules, medicinal chemistry,
and ligand design for transition metals. However, state-of-the-art methods cannot be applied …

The hydrofluorination of alkenes represents an attractive strategy for the synthesis of
aliphatic fluorides. This approach provides a direct means to form C (sp3)–F bonds …

Electrochemically driven hydrogen atom transfer (HAT) catalysis provides a complementary
approach for the transformation of redox-inactive substrates that would be inaccessible to …

Oxidative MHAT hydrofunctionalization of alkenes provides a mild cobalt-catalyzed route to
forming C–N and C–O bonds. Here, we characterize relevant salen-supported cobalt …

Catalytic asymmetric hydroamination of alkenes with Lewis basic amines is of great interest
but remains a challenge in synthetic chemistry. Here, we developed a Co‐catalyzed …

We report a mild, catalytic method for the intermolecular reductive coupling of feedstock
dienes and styrenes with ketones. Our conditions allow concomitant formation of a cobalt …

The direct functionalization of allylic C− H bonds with nucleophiles minimizes pre‐
functionalization and converts inexpensive, abundantly available materials to value‐added …

The catalytic hydrofunctionalization of alkenes through radical-polar crossover metal
hydrogen atom transfer (MHAT) offers a mild pathway for the introduction of functional …