Dynamics of anions: from bound to unbound states and everything In between
Gas-phase anions present an ideal playground for the exploration of excited-state dynamics.
They offer control in terms of the mass, extent of solvation, internal temperature, and …
They offer control in terms of the mass, extent of solvation, internal temperature, and …
State-specific chemical dynamics of the nonvalence bound state of the molecular anions
Conspectus Nonvalence bound states (NBS) are anionic states where the excess electron is
extremely loosely bound to the neutral core through long-range potentials. In contrast to the …
extremely loosely bound to the neutral core through long-range potentials. In contrast to the …
Mode-specific vibrational autodetachment following excitation of electronic resonances by electrons and photons
Electronic resonances commonly decay via internal conversion to vibrationally hot anions
and subsequent statistical electron emission. We observed vibrational structure in such an …
and subsequent statistical electron emission. We observed vibrational structure in such an …
Real-time autodetachment dynamics of vibrational Feshbach resonances in a dipole-bound state
Feshbach resonances corresponding to metastable vibrational states of the dipole-bound
state (DBS) have been interrogated in real time for the first time. The state-specific …
state (DBS) have been interrogated in real time for the first time. The state-specific …
Ultrafast valence to non-valence excited state dynamics in a common anionic chromophore
Non-valence states in neutral molecules (Rydberg states) have well-established roles and
importance in photochemistry, however, considerably less is known about the role of non …
importance in photochemistry, however, considerably less is known about the role of non …
High-resolution photoelectron imaging and resonant photoelectron spectroscopy via noncovalently bound excited states of cryogenically cooled anions
Valence-bound anions with polar neutral cores (μ>∼ 2.5 D) can support dipole-bound
excited states below the detachment threshold. These dipole-bound states (DBSs) are …
excited states below the detachment threshold. These dipole-bound states (DBSs) are …
Experimental observation of the resonant doorways to anion chemistry: dynamic role of dipole-bound Feshbach resonances in dissociative electron attachment
Anion chemical dynamics of autodetachment and fragmentation mediated by the dipole-
bound state (DBS) have been thoroughly investigated in a state-specific way by employing …
bound state (DBS) have been thoroughly investigated in a state-specific way by employing …
Role of nonvalence states in the ultrafast dynamics of isolated anions
Nonvalence states of neutral molecules (Rydberg states) play important roles in
nonadiabatic dynamics of excited states. In anions, such nonadiabatic transitions between …
nonadiabatic dynamics of excited states. In anions, such nonadiabatic transitions between …
Reaction dynamics of the nonvalence bound states of the anions
Nonvalence bound state (NBS) is a unique anionic state where an excess electron is loosely
bound to a neutral molecule in long-range potentials. Since Fermi and Teller first proposed …
bound to a neutral molecule in long-range potentials. Since Fermi and Teller first proposed …
Observation and ultrafast dynamics of a nonvalence correlation-bound state of an anion
JN Bull, JRR Verlet - Science Advances, 2017 - science.org
Nonvalence states of molecular anions play key roles in processes, such as electron
mobility, in rare-gas liquids, radiation-induced damage to DNA, and the formation of anions …
mobility, in rare-gas liquids, radiation-induced damage to DNA, and the formation of anions …