Metal-containing clusters have attracted increasing attention over the past 2–3 decades.
This intense interest can be attributed to the fact that these discrete metal aggregates, whose …

The design and construction of high-nuclear polyoxometalate (POM) clusters remain a
severe challenge, but attract significant interest on account of their impressive structural …

The interest in functional supramolecular systems for the design of innovative materials and
technologies, able to fundamentally change the world, is growing at a high pace. The huge …

In the last five years and currently, research on solar fuels has been intense and no sub-
area in this field has been more active than the development of water oxidation catalysts …

Polyoxometalates (POMs) have demonstrated strong potential in various fields, such as
catalysis, magnetism, medicine, photochemistry and materials science, for their remarkable …

Polyoxometalates represent a diverse range of molecular clusters with an almost unmatched
range of physical properties and the ability to form structures that can bridge several length …

In this review, aspects of the syntheses, structures and magnetic properties of giant 3d and
3d/4f paramagnetic metal clusters in moderate oxidation states are discussed. The term …

Large, hydrophilic polyoxoanions with high solubility in water and/or other polar solvents
demonstrate unique solution behavior by self-assembling into single layer, hollow, spherical …

Following Nature's lessons, today chemists can cross the boundary of the small molecule
world to construct multifunctional and highly complex molecular nano-objects up to protein …

This critical review surveys the 3d substituted magnetic polyoxotungstate (POT) molecular
compounds reported these last ten years, illustrating the huge variety of topologies that …