Metal-coordinated azoaromatics: Strategies for sequential azo-reduction, isomerization and application potential
Reversible electron reservoir feature of redox non-innocent ligand is an important event from
the broader perspectives of metal–ligand cooperativity in catalysis as well as in introducing …
the broader perspectives of metal–ligand cooperativity in catalysis as well as in introducing …
Metal–ligand cooperative approaches in homogeneous catalysis using transition metal complex catalysts of redox noninnocent ligands
Catalysis offers a straightforward route to prepare various value-added molecules starting
from readily available raw materials. The catalytic reactions mostly involve multi-electron …
from readily available raw materials. The catalytic reactions mostly involve multi-electron …
N-Alkylation of Amines by C1–C10 Aliphatic Alcohols Using A Well-Defined Ru(II)-Catalyst. A Metal–Ligand Cooperative Approach
A Ru (II)-catalyzed efficient and selective N-alkylation of amines by C1–C10 aliphatic
alcohols is reported. The catalyst [Ru (L1a)(PPh3) Cl2](1a) bearing a tridentate redox-active …
alcohols is reported. The catalyst [Ru (L1a)(PPh3) Cl2](1a) bearing a tridentate redox-active …
Zn(II)-Catalyzed Selective N-Alkylation of Amines with Alcohols Using Redox Noninnocent Azo-Aromatic Ligand as Electron and Hydrogen Reservoir
We report a sustainable and eco-friendly approach for selective N-alkylation of various
amines by alcohols, catalyzed by a well-defined Zn (II)-catalyst, Zn (La) Cl2 (1a), bearing a …
amines by alcohols, catalyzed by a well-defined Zn (II)-catalyst, Zn (La) Cl2 (1a), bearing a …
A general and practical bifunctional cobalt catalytic system for N-heterocycle assembly via acceptorless dehydrogenation
A novel and highly-efficient N-heterocycle assembly methodology catalyzed by a cobalt-N, N-
bidentate complex has been established. The cobalt complex is unprecedented, phosphine …
bidentate complex has been established. The cobalt complex is unprecedented, phosphine …
Zn (II)-catalyzed multicomponent sustainable synthesis of pyridines in air
Herein, we report a Zn (II)-catalyzed solvent-free sustainable synthesis of tri-and tetra-
substituted pyridines using alcohols as the primary feedstock and NH4OAc as the nitrogen …
substituted pyridines using alcohols as the primary feedstock and NH4OAc as the nitrogen …
Roles of Alkali Metals tert‐Butoxide as Catalysts and Activators in Organic Transformations
The alkali metal tert‐butoxides have found wide application as catalysts and activators for
the conversion of numerous organic molecules. These formidable additives in catalytic …
the conversion of numerous organic molecules. These formidable additives in catalytic …
Alcohol Dehydrogenation-Triggered Selective C3-Alkylation of Indoles by Homogeneous Azo-aromatic Cobalt Catalysts
Herein, we report azo-benzimidazole containing cobalt complexes (1–3) for alcohol
dehydrogenation-triggered C3-alkylation of indoles. In complexes 1–3, ligands are redox …
dehydrogenation-triggered C3-alkylation of indoles. In complexes 1–3, ligands are redox …
Ruthenium-catalyzed dehydrogenative functionalization of alcohols to pyrroles: a comparison between metal–ligand cooperative and non-cooperative approaches
Herein, we report the synthesis and characterization of two ruthenium-based pincer-type
catalysts,[1] X (X= Cl, PF6) and 2, containing two different tridentate pincer ligands, 2 …
catalysts,[1] X (X= Cl, PF6) and 2, containing two different tridentate pincer ligands, 2 …
Nickel catalyzed sustainable synthesis of benzazoles and purines via acceptorless dehydrogenative coupling and borrowing hydrogen approach
Herein we report nickel-catalyzed sustainable synthesis of a few chosen five-membered
fused nitrogen heterocycles such as benzimidazole, purine, benzothiazole, and …
fused nitrogen heterocycles such as benzimidazole, purine, benzothiazole, and …