The late stage functionalization (LSF) of complex biorelevant compounds is a powerful tool
to speed up the identification of structure–activity relationships (SARs) and to optimize …

Alkyl radicals are key intermediates in organic synthesis. Their classic generation from alkyl
halides has a severe drawback due to the employment of toxic tin hydrides to the point that …

The association of an electron-rich substrate with an electron-accepting molecule can
generate a new molecular aggregate in the ground state, called an electron donor–acceptor …

Organoborons have emerged as versatile building blocks in organic synthesis to achieve
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …

We report herein a modular class of organic catalysts that, acting as donors, can readily form
photoactive electron donor–acceptor (EDA) complexes with a variety of radical precursors …

Pyridinium salts are valuable building blocks, which have been widely applied in various
organic transformations during the past few decades. In particular, N-functionalized …

The use of pyridinium‐activated primary amines as photoactive functional groups for
deaminative generation of alkyl radicals under catalyst‐free conditions is described. By …

Sulfonium salts bearing a positively charged sulfur atom with three organic substituents
have intrigued chemists for more than a century for their unusual structures and high …

In this Review, we highlight recent advances in the understanding and design of N‐
functionalized pyridinium scaffolds as redox‐active, single‐electron, functional group …

A systematic, user‐friendly assessment tool that delivers a clear overview of the sensitivity of
reactions to key parameters is highly desirable. Herein, the development of such a method is …