A Review on Regulating Li+ Solvation Structures in Carbonate Electrolytes for Lithium Metal Batteries

Z Piao, R Gao, Y Liu, G Zhou, HM Cheng - Advanced Materials, 2023 - Wiley Online Library
Lithium metal batteries (LMBs) are considered promising candidates for next‐generation
battery systems due to their high energy density. However, commercialized carbonate …

Advanced nonflammable organic electrolyte promises safer li‐metal batteries: from solvation structure perspectives

S Yuan, K Ding, X Zeng, D Bin, Y Zhang… - Advanced …, 2023 - Wiley Online Library
Batteries with a Li‐metal anode have recently attracted extensive attention from the battery
communities owing to their high energy density. However, severe dendrite growth hinders …

Regulating electrode/electrolyte interfacial chemistry enables 4.6 V ultra-stable fast charging of commercial LiCoO 2

A Zhang, Z Bi, G Wang, S Liao, P Das, H Lin… - Energy & …, 2024 - pubs.rsc.org
The difficulty of achieving fast-charging high-voltage lithium-ion batteries arises from
severely unstable electrode–electrolyte interfaces with sluggish kinetics. Here we overcome …

Visualizing and Regulating Dynamic Evolution of Interfacial Electrolyte Configuration during De‐solvation Process on Lithium‐Metal Anode

J Wang, J Luo, H Wu, X Yu, X Wu, Z Li… - Angewandte Chemie …, 2024 - Wiley Online Library
Acting as a passive protective layer, solid‐electrolyte interphase (SEI) plays a crucial role in
maintaining the stability of the Li‐metal anode. Derived from the reductive decomposition of …

Nonflammable electrolyte with low exothermic design for safer lithium-based batteries

S Zhang, S Li, X Wang, C Li, Y Liu, H Cheng, S Mao… - Nano Energy, 2023 - Elsevier
Battery safety has always been a concern for high-energy-density configurations with nickel-
rich cathode (Ni> 0.6). Tremendous heat released from the reaction between highly …

Do** in solvation structure: enabling fluorinated carbonate electrolyte for high-voltage and high-safety lithium-ion batteries

M Qin, Z Zeng, F Ma, C Gu, X Chen, S Cheng… - ACS Energy …, 2024 - ACS Publications
Operating a Ni-rich cathode beyond 4.3 V safely holds promise for boosting the energy
density in lithium-ion batteries (LIBs). Methyl 2, 2, 2-trifluoroethyl carbonate (FEMC) shows …

Structural regulation chemistry of lithium ion solvation for lithium batteries

Z Wang, H Wang, S Qi, D Wu, J Huang, X Li, C Wang… - …, 2022 - Wiley Online Library
The performance of Li batteries is influenced by the Li+ solvation structure, which can be
precisely adjusted by the components of the electrolytes. In this review, we overview the …

Simultaneous Stabilization of Lithium Anode and Cathode using Hyperconjugative Electrolytes for High‐voltage Lithium Metal Batteries

H Zhang, R Li, L Chen, Y Fan, H Zhang… - Angewandte Chemie …, 2023 - Wiley Online Library
Although great progress has been made in new electrolytes for lithium metal batteries
(LMBs), the intrinsic relationship between electrolyte composition and cell performance …

Stabilizing LiCoO 2 at 4.6 V by regulating anti-oxidative solvents

H Ren, G Zheng, Y Li, S Chen, X Wang… - Energy & …, 2024 - pubs.rsc.org
For LiCoO2 (LCO) operating at high voltages (> 4.5 V vs. Li/Li+), the intensive side reactions
between LCO and traditional ethylene carbonate (EC)-based electrolytes with LiPF6 salts …

A bifunctional fluorinated ether co-solvent for dendrite-free and long-term lithium metal batteries

G Zhang, X Deng, J Li, J Wang, G Shi, Y Yang, J Chang… - Nano Energy, 2022 - Elsevier
The employment of localized high concentration electrolytes (LHCEs) has been
demonstrated as an effective strategy for the fabrication of next-generation high-energy …