Arynes are among the most active organic intermediates and have found numerous
applications in expeditious preparation of substituted arenes. In the past 20 years, chemists …

The recent progress made on transformations involving the reactions between aryne
intermediates and organosulfur compounds has been reviewed. A wide variety of aromatic …

The activation of typically unreactive aromatic C–H bonds by transition-metal catalysis has
been receiving increased attention from the synthetic chemistry community in recent years …

Aryl amines are highly useful organic chemicals, but large-scale, transition-metal-free
syntheses of aryl amines are surprisingly underdeveloped. A mild and scalable (up to 500 …

Graphene sheets were spontaneously functionalized with anthraquinone molecules in a one-
pot process, during the oxidative electrochemical exfoliation of a graphite electrode in a 0.1 …

Direct Thioamination of Arynes via Reaction with Sulfilimines and Migratory N-Arylation |
Journal of the American Chemical Society Recently Viewedclose modal ACS ACS Publications …

A new benzyne transformation is described that affords versatile biaryl structures without
recourse to transition‐metal catalysis or stoichiometric amounts of organometallic building …

An efficient deborylthiolation of aryl-and alkenylborons with thiosulfonates has been
achieved under mild conditions using a copper catalyst. All steps of the experimental …

An imine-coupled [Fe–N2S2] 2 complex, prepared from a readily available
benzothiazolidine ligand, catalyzes selectively the hydroboration of aliphatic and aromatic …

A facile synthetic method for preparing 3-amino-2-silylaryl triflates via regioselective
silylamination of 3-(triflyloxy) arynes with N-silylamines is described. Fluoride-mediated …