Metal–organic framework-based catalysts with single metal sites

YS Wei, M Zhang, R Zou, Q Xu - Chemical Reviews, 2020 - ACS Publications
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …

Defective metal‐organic frameworks

S Dissegna, K Epp, WR Heinz, G Kieslich… - Advanced …, 2018 - Wiley Online Library
The targeted incorporation of defects into crystalline matter allows for the manipulation of
many properties and has led to relevant discoveries for optimized and even novel …

Metal–organic frameworks as catalysts for organic synthesis: a critical perspective

V Pascanu, G González Miera, AK Inge… - Journal of the …, 2019 - ACS Publications
Recent advances in organic chemistry and materials chemistry have enabled the porosity of
new materials to be accurately controlled on the nanometer scale. In this context, metal …

Symmetry-breaking dynamics in a tautomeric 3D covalent organic framework

Y Xu, T Sun, T Zeng, X Zhang, X Yao, S Liu… - Nature …, 2023 - nature.com
The enolimine-ketoenamine tautomerism has been utilised to construct 2D covalent organic
frameworks (COFs) with a higher level of chemical robustness and superior photoelectronic …

Anisotropic reticular chemistry

W Xu, B Tu, Q Liu, Y Shu, CC Liang… - Nature Reviews …, 2020 - nature.com
Reticular chemistry has been focused on making simple structures in which a few kinds of
components are linked to make crystals such as metal–organic frameworks (MOFs). While …

Hypersensitive dual-function luminescence switching of a silver-chalcogenolate cluster-based metal–organic framework

RW Huang, YS Wei, XY Dong, XH Wu, CX Du… - Nature …, 2017 - nature.com
Silver (i) chalcogenide/chalcogenolate clusters are promising photofunctional materials for
sensing, optoelectronics and solar energy harvesting applications. However, their instability …

Conceptual and practical aspects of metal–organic frameworks for solid–gas reactions

A Iliescu, JJ Oppenheim, C Sun, M Dincǎ - Chemical Reviews, 2023 - ACS Publications
The presence of site-isolated and well-defined metal sites has enabled the use of metal–
organic frameworks (MOFs) as catalysts that can be rationally modulated. Because MOFs …

Metal–organic framework technologies for water remediation: towards a sustainable ecosystem

M Mon, R Bruno, J Ferrando-Soria… - Journal of materials …, 2018 - pubs.rsc.org
Having access to clean water is a mandatory requirement for the proper development of
living beings. So, addressing the removal of contaminants from aquatic systems should be a …

[HTML][HTML] Mixed component metal-organic frameworks: Heterogeneity and complexity at the service of application performances

M Viciano-Chumillas, X Liu, A Leyva-Pérez… - Coordination Chemistry …, 2022 - Elsevier
The synthesis of mixed-component metal-organic frameworks (MOFs)–including multivariate
MOFs (MTV-MOFs), multicomponent MOFs, mixed-metals MOFs and mixed-ligands and …

The postsynthetic renaissance in porous solids

SM Cohen - Journal of the American Chemical Society, 2017 - ACS Publications
Metal–organic frameworks (MOFs) have rapidly grown into a major area of chemical
research over the last two decades. MOFs represent the development of covalent chemistry …