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Superatoms in materials science
Clusters are ensembles of bound atoms intermediate in size between a molecule and a bulk
solid. Some of these clusters form stable units with atomically precise structures that give …
solid. Some of these clusters form stable units with atomically precise structures that give …
Molecular magnetic materials based on 4d and 5d transition metals
The study of paramagnetic compounds based on 4d and 5d transition metals is an emerging
research topic in the field of molecular magnetism. An essential driving force for the interest …
research topic in the field of molecular magnetism. An essential driving force for the interest …
Single-molecule magnet engineering: building-block approaches
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …
the constituent metal ion building blocks. Although this general approach does not seem to …
The bridging azido ligand as a central “player” in high-nuclearity 3d-metal cluster chemistry
The chemistry of the azido-bridged coordination clusters continues to attract the intense
interest of synthetic inorganic chemists and scientists working in the interdisciplinary field of …
interest of synthetic inorganic chemists and scientists working in the interdisciplinary field of …
Magnetic clusters based on octacyanidometallates
Octacyanidometallates make an important branch of cyanide-based molecular magnets that
not only follow the trends in modern magnetochemistry and materials science but also have …
not only follow the trends in modern magnetochemistry and materials science but also have …
Synthesis of Manganese ZIF-8 from [Mn(BH4)2·3THF]·NaBH4
Cubic and highly porous [Mn (2-methylimidazolate) 2](Mn-ZIF-8) was synthesized from [Mn
(BH4) 2· 3THF]· NaBH4 under an Ar atmosphere. The structure contains rare Mn2+-4N …
(BH4) 2· 3THF]· NaBH4 under an Ar atmosphere. The structure contains rare Mn2+-4N …
New family of thiocyanate-bridged Re (IV)-SCN-M (II)(M= Ni, Co, Fe, and Mn) heterobimetallic compounds: synthesis, crystal structure, and magnetic properties
R Gonzalez, A Acosta, R Chiozzone, C Kremer… - Inorganic …, 2012 - ACS Publications
The heterobimetallic complexes of formula [(Me2phen) 2M (μ-NCS) Re (NCS) 5]· CH3CN
[Me2phen= 2, 9-dimethyl-1, 10-phenanthroline and M= Ni (1), Co (2), Fe (3), and Mn (4)] …
[Me2phen= 2, 9-dimethyl-1, 10-phenanthroline and M= Ni (1), Co (2), Fe (3), and Mn (4)] …
Cyanido-bridged Fe (III)–Mn (III) heterobimetallic materials built from Mn (III) Schiff base complexes and di-or tri-cyanido Fe (III) precursors
T Senapati, C Pichon, R Ababei, C Mathonière… - Inorganic …, 2012 - ACS Publications
The reaction of [FeIIIL (CN) 3]−(L being bpca= bis (2-pyridylcarbonyl) amidate, pcq= 8-
(pyridine-2-carboxamido) quinoline) or [FeIII (bpb)(CN) 2]−(bpb= 1, 2-bis (pyridine-2 …
(pyridine-2-carboxamido) quinoline) or [FeIII (bpb)(CN) 2]−(bpb= 1, 2-bis (pyridine-2 …
Enhancing the Magnetic Coupling of Oxalato-Bridged ReIV2MII (M = Mn, Co, Ni, and Cu) Trinuclear Complexes via Peripheral Halide Ligand Effects
Four heterotrinuclear ReIV2MII compounds of general formula (NBu4) 2 [{ReIVBr4 (μ-ox)}
2MII (Him) 2][NBu4+= tetra-n-butylammonium cation, ox= oxalate, Him= imidazole; M= Mn …
2MII (Him) 2][NBu4+= tetra-n-butylammonium cation, ox= oxalate, Him= imidazole; M= Mn …
Can Anisotropic Exchange Be Reliably Calculated Using Density Functional Methods? A Case Study on Trinuclear MnIII‐MIII‐MnIII (M=Fe, Ru, and Os) …
Density functional studies have been performed on a set of trinuclear single‐molecule
magnets (SMMs) of general formula [{Mn2 (5‐Br salen) 2 (MeOH) 2} M (CN) 6](NEt4)(M …
magnets (SMMs) of general formula [{Mn2 (5‐Br salen) 2 (MeOH) 2} M (CN) 6](NEt4)(M …