Biobased covalent adaptable networks: towards better sustainability of thermosets

XL Zhao, PX Tian, YD Li, JB Zeng - Green Chemistry, 2022 - pubs.rsc.org
Thermosets have many advantages such as excellent mechanical properties, dimensional
stability, and chemical and environmental resistance, but suffer from unsustainability …

Sustainability of self-healing polymers: A holistic perspective towards circularity in polymer networks

K Cerdan, M Thys, AC Cornellà, F Demir… - Progress in Polymer …, 2024 - Elsevier
Permanent polymer networks present an important sustainability challenge. Irreversible
covalent crosslinks impart these materials excellent mechanical properties, thermal and …

Flexible self‐repairing materials for wearable sensing applications: elastomers and hydrogels

S Li, X Zhou, Y Dong, J Li - Macromolecular Rapid …, 2020 - Wiley Online Library
Flexible pressure and strain sensors have great potential for applications in wearable and
implantable devices, soft robots, and artificial skin. The introduction of self‐healing …

Green catalysts for reprocessing thermoset polyurethanes

M Sun, DT Sheppard, JP Brutman, A Alsbaiee… - …, 2023 - ACS Publications
Polyurethane (PU) thermosets are usually landfilled at the end of their service lifetimes and
cannot be recycled through conventional means. Although dibutyltin dilaurate (DBTDL) is an …

Advances in intrinsic self-healing polyurethanes and related composites

B Willocq, J Odent, P Dubois, JM Raquez - RSC advances, 2020 - pubs.rsc.org
Fascinating and challenging, the development of repairable materials with long-lasting,
sustainable and high-performance properties is a key-parameter to provide new advanced …

Thermo-reversible crosslinked natural rubber: A Diels-Alder route for reuse and self-healing properties in elastomers

P Tanasi, MH Santana, J Carretero-González… - Polymer, 2019 - Elsevier
Natural rubber (NR) is one of Nature's most exceptional materials and is, therefore, widely
used by industry, in particular by the tire industry. In spite of the interest in recycling …

Simple approach for a self-healable and stiff polymer network from iminoboronate-based boroxine chemistry

S Delpierre, B Willocq, G Manini, V Lemaur… - Chemistry of …, 2019 - ACS Publications
Despite offering robust mechanical properties, polymer networks suffer from a lack of
recyclability, resha**, and healability. Designing stiff and remendable polymer networks …

A comprehensive review of the structures and properties of ionic polymeric materials

JE Potaufeux, J Odent, D Notta-Cuvier, F Lauro… - Polymer …, 2020 - pubs.rsc.org
Dynamic materials, which include ionic polymeric materials, contain specific bonds or
interactions that can reversibly break and reform under certain stimuli or conditions. Among …

Tailoring the hard–soft interface with dynamic diels–alder linkages in polyurethanes: toward superior mechanical properties and healability at mild temperature

TT Truong, SH Thai, HT Nguyen, DTT Phung… - Chemistry of …, 2019 - ACS Publications
The current thermoremendable polyurethanes (PUs) based on reversible Diels–Alder (DA)
chemistry featuring both good mechanical properties and efficient macrodamage healability …

Double reversible networks: improvement of self-healing in hybrid materials via combination of diels–alder cross-linking and hydrogen bonds

S Schäfer, G Kickelbick - Macromolecules, 2018 - ACS Publications
Intrinsic self-healing materials rely on a reversible bond formation after failure. In this study
we report hybrid materials that contain two intrinsic self-healing forces: The reversible …