The aromatic dianion metalloles

J Wei, WX Zhang, Z ** - Chemical science, 2018 - pubs.rsc.org
Metalloaromatic species are unique and important both experimentally and theoretically.
Significant progress has been made during the past few decades. New aromatic systems …

Aromaticity of group 14 organometallics: Experimental aspects

VY Lee, A Sekiguchi - Angewandte Chemie International …, 2007 - Wiley Online Library
Aromatic compounds have been known for more than 180 years, ever since the discovery by
Faraday in 1825 of the first aromatic hydrocarbon, benzene,[1] whose remarkable cyclic …

Polymer sensors for nitroaromatic explosives detection

SJ Toal, WC Trogler - Journal of Materials Chemistry, 2006 - pubs.rsc.org
Several polymers have been used to detect nitroaromatic explosives by a variety of
transduction schemes. Detection relies on both electronic and structural interactions …

[KNYGA][B] Organometallic compounds of low-coordinate Si, Ge, Sn and Pb: from phantom species to stable compounds

VY Lee, A Sekiguchi - 2011 - books.google.com
Until recently the low-coordinate compounds of the heavier elements of group 14 were
known only as transient, unstable species which were difficult to isolate. However recent …

Silole-containing σ-and π-conjugated compounds

S Yamaguchi, K Tamao - Journal of the Chemical Society, Dalton …, 1998 - pubs.rsc.org
Synthesis, properties, and application of new σ-and π-electron systems consisting of the
silole rings are described. A series of 2, 5-and 1, 1-difunctionalized siloles have been …

Toward new materials for organic electroluminescent devices: synthesis, structures, and properties of a series of 2, 5‐diaryl‐3, 4‐diphenylsiloles

S Yamaguchi, T Endo, M Uchida… - … A European Journal, 2000 - Wiley Online Library
Abstract A series of 2, 5‐diaryl‐3, 4‐diphenylsiloles, with various mono‐substituted phenyl
groups, extended π‐conjugated groups, and heteroaryl groups as aryl groups at the 2, 5 …

Metalloaromaticity

H Masui - Coordination Chemistry Reviews, 2001 - Elsevier
Metalloaromaticity is the manifestation of aromatic properties in the chelate metallacycle,
and was first described by Calvin and Wilson in 1945. The subject has received sporadic …

Synthesis and study of cyclic π-systems containing silicon and germanium. The question of aromaticity in cyclopentadienyl analogues

WP Freeman, TD Tilley, LM Liable-Sands… - Journal of the …, 1996 - ACS Publications
Synthetic routes to the metallole species C4Me4E (H) R (9, E= Si, R= Si (SiMe3) 3; 10, E= Si,
R= Mes (mesityl); 11, E= Ge, R= Si (SiMe3) 3; 12, E= Ge, R= Mes), C4R4E (SiMe3) 2 (13, E …

Group 14 metalloles with thienyl groups on 2, 5-positions: Effects of group 14 elements on their π-electronic structures

S Yamaguchi, Y Itami, K Tamao - Organometallics, 1998 - ACS Publications
A series of group 14 metalloles, from silole to stannole, together with cyclopentadiene,
having two thienyl groups at the 2, 5-positions, have been prepared. Their crystal structures …

A Stable Neutral Silaaromatic Compound, 2-{2, 4, 6-Tris [bis (trimethylsilyl) methyl] phenyl}-2-silanaphthalene

N Tokitoh, K Wakita, R Okazaki, S Nagase… - Journal of the …, 1997 - ACS Publications
Much attention has been focused on the chemistry of silaaromatic compounds, ie, Si-
containing [4n+ 2] π ring systems, and a number of reports on the formation and reactions of …