Stereochemical enhancement of polymer properties
The importance of stereochemistry to the function of molecules is generally well understood.
However, to date, control over stereochemistry and its potential to influence properties of the …
However, to date, control over stereochemistry and its potential to influence properties of the …
Biosynthetic polymers as functional materials
The synthesis of functional polymers encoded with biomolecules has been an extensive
area of research for decades. As such, a diverse toolbox of polymerization techniques and …
area of research for decades. As such, a diverse toolbox of polymerization techniques and …
Isospecific, chain shuttling polymerization of propylene oxide using a bimetallic chromium catalyst: a new route to semicrystalline polyols
MI Childers, AK Vitek, LS Morris… - Journal of the …, 2017 - ACS Publications
Hydroxy-telechelic poly (propylene oxide)(PPO) is widely used industrially as a midsegment
in polyurethane synthesis. These atactic polymers are produced from racemic propylene …
in polyurethane synthesis. These atactic polymers are produced from racemic propylene …
Chiral diboranes as catalysts for the stereoselective organopolymerization of epoxides
A Sirin-Sariaslan, S Naumann - Chemical Science, 2022 - pubs.rsc.org
It is demonstrated that stereoselective polymerization of epoxides, long a domain of metal-
based compounds, can also be achieved via the application of organocatalysts. A simple …
based compounds, can also be achieved via the application of organocatalysts. A simple …
Recent progress in block copolymer crystallization
RM Van Horn, MR Steffen… - Polymer Crystallization, 2018 - Wiley Online Library
Block copolymers (BCPs) are important for technological advances in numerous industries,
including but not limited to, electronics, biomedical, optics, environmental, and infrastructure …
including but not limited to, electronics, biomedical, optics, environmental, and infrastructure …
Bimetallic chromium catalysts with chain transfer agents: a route to isotactic poly (propylene oxide) s with narrow dispersities
LS Morris, MI Childers, GW Coates - Angewandte Chemie, 2018 - Wiley Online Library
Bimetallic chromium catalysts are investigated for the enantioselective polymerization of
propylene oxide. The catalyst is composed of two salen chromium species linked by an alkyl …
propylene oxide. The catalyst is composed of two salen chromium species linked by an alkyl …
A guide to modern methods for poly (thio) ether synthesis using Earth-abundant metals
Polyethers and polythioethers have a long and storied history dating back to the start of
polymer science as a distinct field. As such, these materials have been utilized in a wide …
polymer science as a distinct field. As such, these materials have been utilized in a wide …
Compositionally controlled polyether membranes via mono (μ-alkoxo) bis (alkylaluminum)-initiated chain-growth network epoxide polymerization: synthesis and …
The addition of a diglycidyl-ether to a mono (μ-alkoxo) bis (alkylaluminum)-initiated epoxide
polymerization presents a strategy for amorphous polyether-based membrane synthesis. In …
polymerization presents a strategy for amorphous polyether-based membrane synthesis. In …
Fully amorphous atactic and isotactic block copolymers and their self-assembly into nano-and microscopic vesicles
R Wehr, EC Dos Santos, MS Muthwill, V Chimisso… - Polymer …, 2021 - pubs.rsc.org
The introduction of chirality into aqueous self-assemblies by employing isotactic block
copolymers (BCPs) is an emerging field of interest as it promises special membrane …
copolymers (BCPs) is an emerging field of interest as it promises special membrane …
Manganese (iii) salophen supported on a silica containing triazine dendrimer: An efficient catalyst for epoxidation of alkenes with sodium periodate
In this paper, Mn (III) salophen supported on a nanosilica triazine dendrimer was
synthesized and characterized by FT-IR, UV-vis spectroscopic methods, SEM, TEM, TGA …
synthesized and characterized by FT-IR, UV-vis spectroscopic methods, SEM, TEM, TGA …