Metal species with different size (single atoms, nanoclusters, and nanoparticles) show
different catalytic behavior for various heterogeneous catalytic reactions. It has been shown …

The use of well-defined materials in heterogeneous catalysis will open up numerous new
opportunities for the development of advanced catalysts to address the global challenges in …

Heterogeneous catalysis involves solid-state catalysts, among which metal nanoparticles
occupy an important position. Unfortunately, no two nanoparticles from conventional …

The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …

Single metal atoms and metal clusters have attracted much attention thanks to their
advantageous capabilities as heterogeneous catalysts. However, the generation of stable …

Crystalline nanoporous materials with uniform porous structures, such as zeolites and metal–
organic frameworks (MOFs), have proven to be ideal supports to encapsulate ultrasmall …

Pillararene/calixarene-based functional materials have garnered significant attention for
their unique topological/chemical structures and physicochemical properties, and their …

Atomically dispersing metal atoms on supports provides an ideal strategy for maximizing
metal utilization for catalysis, which is particularly important for fabricating cost‐effective …

Sub-nanometric Pd clusters on porous nanorods of CeO2 (PN-CeO2) with a high Pd
dispersion of 73.6% exhibit the highest catalytic activity and best chemoselectivity for …

Atomically monodispersed heterogeneous catalysts with uniform active sites and high atom
utilization efficiency are ideal heterogeneous catalytic materials. Designing such type of …