Energy transfer catalysis mediated by visible light: principles, applications, directions

F Strieth-Kalthoff, MJ James, M Teders… - Chemical Society …, 2018 - pubs.rsc.org
Harnessing visible light to access excited (triplet) states of organic compounds can enable
impressive reactivity modes. This tutorial review covers the photophysical fundamentals and …

Spin-vibronic mechanism for intersystem crossing

TJ Penfold, E Gindensperger, C Daniel… - Chemical …, 2018 - ACS Publications
Intersystem crossing (ISC), formally forbidden within nonrelativistic quantum theory, is the
mechanism by which a molecule changes its spin state. It plays an important role in the …

The photophysics of photoredox catalysis: a roadmap for catalyst design

DM Arias-Rotondo, JK McCusker - Chemical Society Reviews, 2016 - pubs.rsc.org
Recently, the use of transition metal based chromophores as photo-induced single-electron
transfer reagents in synthetic organic chemistry has opened up a wealth of possibilities for …

Green synthesis of nanoparticles for varied applications: Green renewable resources and energy-efficient synthetic routes

M Madani, S Hosny, DM Alshangiti, N Nady… - Nanotechnology …, 2022 - degruyter.com
This study presents an outline of the 12 principles of green relevance in nanomaterial
synthesis. The goal of using green renewable resources is to protect the environment from …

Is iron the new ruthenium?

OS Wenger - Chemistry–A European Journal, 2019 - Wiley Online Library
Ruthenium complexes with polypyridine ligands are very popular choices for applications in
photophysics and photochemistry, for example, in lighting, sensing, solar cells, and …

A photosensitizer–polyoxometalate dyad that enables the decoupling of light and dark reactions for delayed on-demand solar hydrogen production

S Amthor, S Knoll, M Heiland, L Zedler, C Li… - Nature Chemistry, 2022 - nature.com
Decoupling the production of solar hydrogen from the diurnal cycle is a key challenge in
solar energy conversion, the success of which could lead to sustainable energy schemes …

Charge‐transfer and spin‐flip states: Thriving as complements

WR Kitzmann, K Heinze - Angewandte Chemie International …, 2023 - Wiley Online Library
Transition metal complexes with photoactive charge‐transfer excited states are pervasive
throughout the literature. In particular,[Ru (bpy) 3] 2+(bpy= 2, 2′‐bipyridine), with its metal …

Cobalt (III) carbene complex with an electronic excited-state structure similar to cyclometalated iridium (III) compounds

N Sinha, B Pfund, C Wegeberg… - Journal of the …, 2022 - ACS Publications
Many organometallic iridium (III) complexes have photoactive excited states with mixed
metal-to-ligand and intraligand charge transfer (MLCT/ILCT) character, which form the basis …

Ultrafast electron dynamics in solar energy conversion

CS Ponseca Jr, P Chábera, J Uhlig, P Persson… - Chemical …, 2017 - ACS Publications
Electrons are the workhorses of solar energy conversion. Conversion of the energy of light to
electricity in photovoltaics, or to energy-rich molecules (solar fuel) through photocatalytic …

Beyond click chemistry–supramolecular interactions of 1, 2, 3-triazoles

B Schulze, US Schubert - Chemical Society Reviews, 2014 - pubs.rsc.org
The research on 1, 2, 3-triazoles has been lively and ever-growing since its stimulation by
the advent of click chemistry. The attractiveness of 1H-1, 2, 3-triazoles and their derivatives …