Bioinspired framework catalysts: From enzyme immobilization to biomimetic catalysis

KY Wang, J Zhang, YC Hsu, H Lin, Z Han… - Chemical …, 2023 - ACS Publications
Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …

Metal–organic frameworks in heterogeneous catalysis: recent progress, new trends, and future perspectives

A Bavykina, N Kolobov, IS Khan, JA Bau… - Chemical …, 2020 - ACS Publications
More than 95%(in volume) of all of today's chemical products are manufactured through
catalytic processes, making research into more efficient catalytic materials a thrilling and …

Surface coordination chemistry of atomically dispersed metal catalysts

R Qin, K Liu, Q Wu, N Zheng - Chemical Reviews, 2020 - ACS Publications
Atomically dispersed metal catalysts (ADCs), as an emerging class of heterogeneous
catalysts, have been widely investigated during the past two decades. The atomic dispersion …

Improving MOF stability: approaches and applications

M Ding, X Cai, HL Jiang - Chemical Science, 2019 - pubs.rsc.org
Metal–organic frameworks (MOFs) have been recognized as one of the most important
classes of porous materials due to their unique attributes and chemical versatility …

Atomic-level design of metalloenzyme-like active pockets in metal–organic frameworks for bioinspired catalysis

W Xu, Y Wu, W Gu, D Du, Y Lin, C Zhu - Chemical Society Reviews, 2024 - pubs.rsc.org
Natural metalloenzymes with astonishing reaction activity and specificity underpin essential
life transformations. Nevertheless, enzymes only operate under mild conditions to keep …

Metal–organic frameworks against toxic chemicals

T Islamoglu, Z Chen, MC Wasson, CT Buru… - Chemical …, 2020 - ACS Publications
Materials capable of the safe and efficient capture or degradation of toxic chemicals,
including chemical warfare agents (CWAs) and toxic industrial chemicals (TICs), are …

Nanozymes: classification, catalytic mechanisms, activity regulation, and applications

Y Huang, J Ren, X Qu - Chemical reviews, 2019 - ACS Publications
Because of the high catalytic activities and substrate specificity, natural enzymes have been
widely used in industrial, medical, and biological fields, etc. Although promising, they often …

Nanomaterials with enzyme-like characteristics (nanozymes): next-generation artificial enzymes (II)

J Wu, X Wang, Q Wang, Z Lou, S Li, Y Zhu… - Chemical Society …, 2019 - pubs.rsc.org
Nanozymes are nanomaterials with enzyme-like characteristics (Chem. Soc. Rev., 2013, 42,
6060–6093). They have been developed to address the limitations of natural enzymes and …

Generating catalytic sites in UiO-66 through defect engineering

X Feng, HS Jena, C Krishnaraj, K Leus… - … Applied Materials & …, 2021 - ACS Publications
UiO-66 is regarded as an epitome of metal–organic frameworks (MOFs) because of its
stability. Defect engineering has been used as a toolbox to alter the performance of MOFs …

Reaction mechanisms and kinetics of nanozymes: insights from theory and computation

X Shen, Z Wang, XJ Gao, X Gao - Advanced Materials, 2024 - Wiley Online Library
Abstract “Nanozymes” usually refers to inorganic nanomaterials with enzyme‐like catalytic
activities. The research into nanozymes is one of the hot topics on the horizon of …