O2 Activation by Metal Surfaces: Implications for Bonding and Reactivity on Heterogeneous Catalysts

MM Montemore, MA Van Spronsen, RJ Madix… - Chemical …, 2017 - ACS Publications
The activation of O2 on metal surfaces is a critical process for heterogeneous catalysis and
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …

Nanocatalysis: size-and shape-dependent chemisorption and catalytic reactivity

BR Cuenya, F Behafarid - Surface Science Reports, 2015 - Elsevier
In recent years, the field of catalysis has experienced an astonishing transformation, driven
in part by more demanding environmental standards and critical societal and industrial …

Surface chemistry of ruthenium dioxide in heterogeneous catalysis and electrocatalysis: from fundamental to applied research

H Over - Chemical Reviews, 2012 - ACS Publications
Ruthenium is a chemical element that can easily adopt various formal oxidation states from−
II to+ VIII in chemical bonds,(1, 2) thus giving rise to many compounds with interesting and …

Synthesis and catalytic properties of metal nanoparticles: Size, shape, support, composition, and oxidation state effects

BR Cuenya - Thin Solid Films, 2010 - Elsevier
Exciting new opportunities are emerging in the field of catalysis based on nanotechnology
approaches. A new understanding and mastery of catalysis could have broad societal …

Structure dependency of the atomic-scale mechanisms of platinum electro-oxidation and dissolution

T Fuchs, J Drnec, F Calle-Vallejo, N Stubb… - Nature Catalysis, 2020 - nature.com
Platinum dissolution and restructuring due to surface oxidation are primary degradation
mechanisms that limit the lifetime of platinum-based electrocatalysts for electrochemical …

Anodic and cathodic platinum dissolution processes involve different oxide species

T Fuchs, V Briega‐Martos, J Drnec, N Stubb… - Angewandte …, 2023 - Wiley Online Library
The degradation of Pt‐containing oxygen reduction catalysts for fuel cell applications is
strongly linked to the electrochemical surface oxidation and reduction of Pt. Here, we study …

Suppressing dissolution of Pt‐based electrocatalysts through the electronic metal–support interaction

G Lin, Q Ju, Y **, X Qi, W Liu… - Advanced Energy …, 2021 - Wiley Online Library
Suppressing the Pt dissolution still remains a big challenge in improving the long‐term
stability of Pt‐based catalysts in electrochemical energy conversion. In this work, the …

Observing the oxidation of platinum

MA Van Spronsen, JWM Frenken, IMN Groot - Nature communications, 2017 - nature.com
Despite its importance in oxidation catalysis, the active phase of Pt remains uncertain, even
for the Pt (111) single-crystal surface. Here, using a ReactorSTM, the catalytically relevant …

Surface chemistry of late transition metal oxides

JF Weaver - Chemical reviews, 2013 - ACS Publications
The surface chemistry of late transition metal oxides is scientifically interesting and can play
a central role in commercial applications of heterogeneous catalysis. The late transition …

Reactivity of Chemisorbed Oxygen Atoms and Their Catalytic Consequences during CH4–O2 Catalysis on Supported Pt Clusters

YH Chin, C Buda, M Neurock… - Journal of the American …, 2011 - ACS Publications
Kinetic and isotopic data and density functional theory treatments provide evidence for the
elementary steps and the active site requirements involved in the four distinct kinetic …