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O2 Activation by Metal Surfaces: Implications for Bonding and Reactivity on Heterogeneous Catalysts
The activation of O2 on metal surfaces is a critical process for heterogeneous catalysis and
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …
Nanocatalysis: size-and shape-dependent chemisorption and catalytic reactivity
In recent years, the field of catalysis has experienced an astonishing transformation, driven
in part by more demanding environmental standards and critical societal and industrial …
in part by more demanding environmental standards and critical societal and industrial …
Surface chemistry of ruthenium dioxide in heterogeneous catalysis and electrocatalysis: from fundamental to applied research
H Over - Chemical Reviews, 2012 - ACS Publications
Ruthenium is a chemical element that can easily adopt various formal oxidation states from−
II to+ VIII in chemical bonds,(1, 2) thus giving rise to many compounds with interesting and …
II to+ VIII in chemical bonds,(1, 2) thus giving rise to many compounds with interesting and …
Synthesis and catalytic properties of metal nanoparticles: Size, shape, support, composition, and oxidation state effects
BR Cuenya - Thin Solid Films, 2010 - Elsevier
Exciting new opportunities are emerging in the field of catalysis based on nanotechnology
approaches. A new understanding and mastery of catalysis could have broad societal …
approaches. A new understanding and mastery of catalysis could have broad societal …
Structure dependency of the atomic-scale mechanisms of platinum electro-oxidation and dissolution
Platinum dissolution and restructuring due to surface oxidation are primary degradation
mechanisms that limit the lifetime of platinum-based electrocatalysts for electrochemical …
mechanisms that limit the lifetime of platinum-based electrocatalysts for electrochemical …
Anodic and cathodic platinum dissolution processes involve different oxide species
The degradation of Pt‐containing oxygen reduction catalysts for fuel cell applications is
strongly linked to the electrochemical surface oxidation and reduction of Pt. Here, we study …
strongly linked to the electrochemical surface oxidation and reduction of Pt. Here, we study …
Suppressing dissolution of Pt‐based electrocatalysts through the electronic metal–support interaction
G Lin, Q Ju, Y **, X Qi, W Liu… - Advanced Energy …, 2021 - Wiley Online Library
Suppressing the Pt dissolution still remains a big challenge in improving the long‐term
stability of Pt‐based catalysts in electrochemical energy conversion. In this work, the …
stability of Pt‐based catalysts in electrochemical energy conversion. In this work, the …
Observing the oxidation of platinum
Despite its importance in oxidation catalysis, the active phase of Pt remains uncertain, even
for the Pt (111) single-crystal surface. Here, using a ReactorSTM, the catalytically relevant …
for the Pt (111) single-crystal surface. Here, using a ReactorSTM, the catalytically relevant …
Surface chemistry of late transition metal oxides
JF Weaver - Chemical reviews, 2013 - ACS Publications
The surface chemistry of late transition metal oxides is scientifically interesting and can play
a central role in commercial applications of heterogeneous catalysis. The late transition …
a central role in commercial applications of heterogeneous catalysis. The late transition …
Reactivity of Chemisorbed Oxygen Atoms and Their Catalytic Consequences during CH4–O2 Catalysis on Supported Pt Clusters
Kinetic and isotopic data and density functional theory treatments provide evidence for the
elementary steps and the active site requirements involved in the four distinct kinetic …
elementary steps and the active site requirements involved in the four distinct kinetic …