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[HTML][HTML] Inspired by Nature—Functional Analogues of Molybdenum and Tungsten-Dependent Oxidoreductases
S Pätsch, JV Correia, BJ Elvers, M Steuer, C Schulzke - Molecules, 2022 - mdpi.com
Throughout the previous ten years many scientists took inspiration from natural molybdenum
and tungsten-dependent oxidoreductases to build functional active site analogues. These …
and tungsten-dependent oxidoreductases to build functional active site analogues. These …
Reactivity of metal dioxo complexes
CA Canote, SM Kilyanek - Dalton Transactions, 2024 - pubs.rsc.org
Metal dioxo chemistry and its diverse reactivity are presented with an emphasis on the
mechanisms of reactivity. Work from approximately the last decade is surveyed and …
mechanisms of reactivity. Work from approximately the last decade is surveyed and …
Replacement of molybdenum by tungsten in a biomimetic complex leads to an increase in oxygen atom transfer catalytic activity
Upon replacement of molybdenum by tungsten in DMSO reductase isolated from the
Rhodobacteraceae family, the derived enzyme catalyzes DMSO reduction faster. To better …
Rhodobacteraceae family, the derived enzyme catalyzes DMSO reduction faster. To better …
Dioxo-, oxo-imido-, and bis-imido-molybdenum (VI) complexes with a bis-phenolate-NHC ligand
We report the facile synthesis of five rare high-valent Mo (VI)-NHC complexes with a
dianionic OCO-pincer benzimidazolylidene ligand (L1) with the general formula L1MoO2 …
dianionic OCO-pincer benzimidazolylidene ligand (L1) with the general formula L1MoO2 …
Influence of the pendant arm in deoxydehydration catalyzed by dioxomolybdenum complexes supported by amine bisphenolate ligands
Dioxomolybdenum complexes supported by aminebisphenolate ligands were evaluated for
their potential in catalyzing the deoxydehydration (DODH) reaction to establish structure …
their potential in catalyzing the deoxydehydration (DODH) reaction to establish structure …
A dioxidomolybdenum (VI) complex chelated with salicylaldehyde-3-methoxybenzhydrazone: Synthesis, crystal structure and catalytic activity
Abstract A dioxidomolybdenum (VI) complex,[MoO 2 (SMBH)(DMSO)] derived from tridentate
ONO aroylhydrazone, salicylaldehyde-3-methoxybenzhydrazone (SMBH 2), has been …
ONO aroylhydrazone, salicylaldehyde-3-methoxybenzhydrazone (SMBH 2), has been …
[HTML][HTML] Amide functionalized aminobisphenolato MoO2 and WO2 complexes: Synthesis, characterization, and alkene epoxidation catalysis
The use of dioxidomolybdenum (vi) and-tungsten (vi) complexes supported by a variety of
structurally different tri-and tetradentate aminobisphenolato ligands as pre-catalysts in the …
structurally different tri-and tetradentate aminobisphenolato ligands as pre-catalysts in the …
Synthesis and X-ray crystal structure of a Molybdenum (VI) Schiff base complex: Design of a new catalytic system for sustainable olefin epoxidation
A targeted new dioxo molybdenum (VI) ONO Schiff base complex was prepared for
catalyzing epoxidation of olefins in water. This complex was characterized by FT-IR, NMR …
catalyzing epoxidation of olefins in water. This complex was characterized by FT-IR, NMR …
The Syntheses and Vibrational Spectra of 16O‐ and 18O‐Enriched cis‐MO2 (M=Mo, W) Complexes
In this contribution, we report convenient synthetic approaches for obtaining 16O/18O‐
enriched dioxidometalVI complexes, MO2 (L)(W, Mo), with a linear, tetradentate amine …
enriched dioxidometalVI complexes, MO2 (L)(W, Mo), with a linear, tetradentate amine …
Dioxidomolybdenum (VI) and–tungsten (VI) complexes with tetradentate amino bisphenolates as catalysts for epoxidation
Sixteen molybdenum and tungsten complexes with tripodal or linear tetradentate amino
bisphenol ligands were studied as catalysts for the epoxidation of cis-cyclooctene, 1-octene …
bisphenol ligands were studied as catalysts for the epoxidation of cis-cyclooctene, 1-octene …