The use of 3d metals in de/hydrogenation catalysis has emerged as a competitive field with
respect to “traditional” precious metal catalyzed transformations. The introduction of …

Cobalt has become increasingly attractive in homogeneous catalysis because of its unique
characteristics and outstanding catalytic performance in addition to being cheap and earth …

Homogeneous catalysis of organic transformations by metal complexes has been mostly
based on complexes of noble metals. In recent years, tremendous progress has been made …

Non‐noble metal catalysts based on pincer type compounds are of special interest for
organometallic chemistry and organic synthesis. Next to iron and manganese, currently …

Owing to availability of various hydrogen sources, operational simplicity, and mild reaction
conditions, catalytic transfer hydrogenation (TH) has emerged as an appealing alternative …

Direct synthesis of N-heterocycles via the acceptorless dehydrogenative coupling is very
challenging and scarcely reported under 3d transition-metal catalysis. Here, we have …

The selective semihydrogenation of alkynes to (E)-alkenes is a challenging transformation
that is of significant synthetic interest. The development of direct hydrogenation catalysts for …

Chemoselective semihydrogenation of alkynes to alkenes with E-or Z-stereoselectivity is
among the most important transformations in the synthesis of highly functional organic …

In recent times, earth-abundant 3d-transition-metal catalysts have attracted much attention in
contemporary catalysis. They have been widely employed as suitable alternatives to their …

Transfer hydrogenation (TH) with in situ generated hydrogen donor is of great importance in
reduction reactions, and an alternative strategy to traditional hydrogenation processes …