Origins of non-ideal behaviour in voltammetric analysis of redox-active monolayers

BL Huffman, ARC Bredar, JL Dempsey - Nature Reviews Chemistry, 2024 - nature.com
Disorder in redox-active monolayers convolutes electrochemical characterization. This
disorder can come from pinhole defects, loose packing, heterogeneous distribution of redox …

Functionalization of oxide-free silicon surfaces with redox-active assemblies

B Fabre - Chemical Reviews, 2016 - ACS Publications
This review provides a comprehensive survey of the derivatization of hydrogen-terminated,
oxide-free silicon surfaces with electroactive assemblies (from molecules to polymers) …

Single molecular conductance of tolanes: experimental and theoretical study on the junction evolution dependent on the anchoring group

W Hong, DZ Manrique, P Moreno-García… - Journal of the …, 2012 - ACS Publications
Employing a scanning tunneling microscopy based beak junction technique and
mechanically controlled break junction experiments, we investigated tolane …

Quantitative analysis of cyclic voltammetry of redox monolayers adsorbed on semiconductors: isolating electrode kinetics, lateral interactions, and diode currents

YB Vogel, A Molina, J Gonzalez, S Ciampi - Analytical chemistry, 2019 - ACS Publications
The design of devices whose functions span from sensing their environments to converting
light into electricity or guiding chemical reactivity at surfaces often hinges around a correct …

Electrochemically-gated single-molecule electrical devices

S Guo, JM Artés, I Díez-Pérez - Electrochimica Acta, 2013 - Elsevier
In the last decade, single-molecule electrical contacts have emerged as a new experimental
platform that allows exploring charge transport phenomena in individual molecular blocks …

Investigation on novel redox-responsive ferrocenyl surfactants with reversible interfacial behavior and their recycling application for enhanced oil recovery

H Jia, J He, Q Wang, Y Xu, L Zhang, H Jia… - Colloids and Surfaces A …, 2022 - Elsevier
Stimuli responsive surfactants with reversible properties may effectively solve the problems
of traditional surfactants (the switching of interfacial activity and the demulsification difficulty …

Thiol–Ene Chemistry of Vinylferrocene: A Simple and Versatile Access Route to Novel Electroactive Sulfur-and Ferrocene-Containing Model Compounds and …

I Martinez-Montero, S Bruna… - …, 2014 - ACS Publications
The potential of vinylferrocene Fc (CH CH2)(1) as redox-active ene functional precursor for
thiol–ene radical reaction has been successfully investigated for the first time. To this end …

Towards the design of effective multipodal contacts for use in the construction of Langmuir–Blodgett films and molecular junctions

E Escorihuela, P Cea, S Bock, DC Milan… - Journal of Materials …, 2020 - pubs.rsc.org
As part of on-going efforts to optimize the electrical performance and stability of molecular
electronic components, anchor groups that bind molecules to electrode surfaces via multiple …

Synthesis, electrochemistry, and optical properties of highly conjugated alkynyl-ferrocenes and-biferrocenes

TLR Bennett, LA Wilkinson, JMA Lok… - …, 2021 - ACS Publications
Sonogashira reactions are utilized herein to react iodo-ferrocenes and-biferrocenes with
terminal alkyne ligands, functionalized with both pyridine and thioanisole groups. High …

Micropatterned ferrocenyl monolayers covalently bound to hydrogen-terminated silicon surfaces: effects of pattern size on the cyclic voltammetry and capacitance …

B Fabre, SP Pujari, L Scheres, H Zuilhof - Langmuir, 2014 - ACS Publications
The effect of the size of patterns of micropatterned ferrocene (Fc)-functionalized, oxide-free n-
type Si (111) surfaces was systematically investigated by electrochemical methods …