This review describes the development of enantioselective methods for the ring opening of
cyclopropanes. Both approaches based on the reaction of nonchiral cyclopropanes and …

Complex molecular architectures containing cyclopropanes present significant challenges
for any synthetic chemist. This review aims to highlight the strategic considerations for …

Arynes and donor–acceptor (D–A) cyclopropanes are two classes of strained systems
having the potential for numerous applications in organic synthesis. The last two decades …

This review summarizes research directed towards the formation of carbocyclic adducts from
donor–acceptor cyclopropanes. The focus of the review is on annulation and cycloaddition …

Recent developments in the stereoselective synthesis of polysubstituted cyclopropanes
nowadays allow chemists to easily access these strained rings with high diastereo-and …

Ring-opening transformations of donor–acceptor cyclopropanes (DAC) with carbon-
centered nucleophiles is a simple, straight-forward approach to 1, 3-bifunctional compounds …

Saturated bicycles are becoming ever more important in the design and development of new
pharmaceuticals. Here a new strategy for the synthesis of bicyclo [2.1. 1] hexanes is …

Enoldiazo esters and amides have proven to be versatile reagents for cycloaddition
reactions that allow highly efficient construction of various carbocycles and heterocycles …

In addition to the appealing synthetic transformations that cyclopropanes present, they are
also part of larger molecular structures that possess a wide range of biological properties …

Cyclization and annulation reactions initiated by ring-opening of small rings, especially
cyclopropanes and cyclobutanes are now well-established in synthetic chemistry …