Molecular spins for quantum computation

A Gaita-Ariño, F Luis, S Hill, E Coronado - Nature chemistry, 2019 - nature.com
Spins in solids or in molecules possess discrete energy levels, and the associated quantum
states can be tuned and coherently manipulated by means of external electromagnetic …

Strategies to quench quantum tunneling of magnetization in lanthanide single molecule magnets

A Swain, T Sharma, G Rajaraman - Chemical Communications, 2023 - pubs.rsc.org
Enhancing blocking temperature (TB) is one of the holy grails in Single Molecule Magnets
(SMMs), as any future potential application in this class of molecules is directly correlated to …

A stable pentagonal bipyramidal Dy (III) single-ion magnet with a record magnetization reversal barrier over 1000 K

J Liu, YC Chen, JL Liu, V Vieru, L Ungur… - Journal of the …, 2016 - ACS Publications
Single-molecule magnets (SMMs) with a large spin reversal barrier have been recognized to
exhibit slow magnetic relaxation that can lead to a magnetic hysteresis loop. Synthesis of …

Strategies toward high-temperature lanthanide-based single-molecule magnets

L Ungur, LF Chibotaru - Inorganic Chemistry, 2016 - ACS Publications
Lanthanide-based single-molecule magnets are leading materials for achieving
magnetization blocking at the level of one molecule. In this paper, we examine the physical …

Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategies

P Zhang, YN Guo, J Tang - Coordination Chemistry Reviews, 2013 - Elsevier
The last few years have seen a huge renaissance in the study of the magnetism of
lanthanide coordination complexes, especially in the field of single molecule magnets …

Playing with organic radicals as building blocks for functional molecular materials

I Ratera, J Veciana - Chemical Society Reviews, 2012 - pubs.rsc.org
The literature has shown numerous contributions on the synthesis and physicochemical
properties of persistent organic radicals but there are a lesser number of reports about their …

Equatorially coordinated lanthanide single ion magnets

P Zhang, L Zhang, C Wang, S Xue… - Journal of the …, 2014 - ACS Publications
The magnetic relaxation dynamics of low-coordinate DyIII and ErIII complexes, namely three-
coordinate ones with an equatorially coordinated triangle geometry and five-coordinate …

Molecular spintronics using single-molecule magnets

L Bogani, W Wernsdorfer - Nature materials, 2008 - nature.com
A revolution in electronics is in view, with the contemporary evolution of the two novel
disciplines of spintronics and molecular electronics. A fundamental link between these two …

Lanthanide double-decker complexes functioning as magnets at the single-molecular level

N Ishikawa, M Sugita, T Ishikawa… - Journal of the …, 2003 - ACS Publications
Double-decker phthalocyanine complexes with Tb3+ or Dy3+ showed slow magnetization
relaxation as a single-molecular property. The temperature ranges in which the behavior …

Quantum tunneling of magnetization and related phenomena in molecular materials

D Gatteschi, R Sessoli - Angewandte Chemie International …, 2003 - Wiley Online Library
Molecules comprising a large number of coupled paramagnetic centers are attracting much
interest because they may show properties which are intermediate between those of simple …