New principles for glycoside‐bond formation

X Zhu, RR Schmidt - Angewandte Chemie International Edition, 2009 - Wiley Online Library
Meeting the demand for sugars: The importance of oligosaccharides and glycoconjugates in
biological systems has stimulated a need to access significant amounts of these …

Site-selective functionalization of hydroxyl groups in carbohydrate derivatives

V Dimakos, MS Taylor - Chemical reviews, 2018 - ACS Publications
Methods for site-selective transformations of hydroxyl groups in carbohydrate derivatives are
reviewed. The construction of oligosaccharides of defined connectivity hinges on such …

Armed–disarmed effects in carbohydrate chemistry: history, synthetic and mechanistic studies

B Fraser-Reid, JC López - Reactivity Tuning in Oligosaccharide Assembly, 2011 - Springer
This chapter begins with an account of the serendipitous events that led to the development
of n-pentenyl glycosides (NPGs) as glycosyl donors, followed by the chance events that laid …

Bringing color to sugars: The chemical assembly of carbohydrates to BODIPY dyes

AM Gomez, JC Lopez - The Chemical Record, 2021 - Wiley Online Library
The combination of carbohydrates with BODIPY fluorophores gives rise to a family of
BODIPY‐carbohydrate hybrids or glyco‐BODIPYs, which mutually benefit from the …

Synthesis of a 28-mer oligosaccharide core of Mycobacterial lipoarabinomannan (LAM) requires only two n-pentenyl orthoester progenitors

B Fraser-Reid, J Lu, KN Jayaprakash, JC Lopez - Tetrahedron: Asymmetry, 2006 - Elsevier
Regioselective glycosidation of acceptor polyols greatly reduces the number of orthogonal
protecting groups that are normally required for conventional syntheses of highly branched …

Potent Fluoro‐oligosaccharide Probes of Adhesion in Toxoplasmosis

SA Allman, HH Jensen, B Vijayakrishnan… - …, 2009 - Wiley Online Library
Unnatural, NMR‐and MRI‐active fluorinated sugar probes, designed and synthesised to
bind to the pathogenic protein TgMIC1 from Toxoplasma gondii, were found to display …

BODIPYs as chemically stable fluorescent tags for synthetic glycosylation strategies towards fluorescently labeled saccharides

C Uriel, C Permingeat, J Ventura… - … A European Journal, 2020 - Wiley Online Library
A series of fluorescent boron‐dipyrromethene (BODIPY, 4, 4‐difluoro‐4‐bora‐3a, 4a‐diaza‐
s‐indacene) dyes have been designed to participate, as aglycons, in synthetic …

Neue Prinzipien für die Bildung von glycosidischen Bindungen

X Zhu, RR Schmidt - Angewandte Chemie, 2009 - Wiley Online Library
Abstract Die wichtige Rolle, die Oligosaccharide und Glycokonjugate in biologischen
Systemen spielen, erfordert immer neue und vor allem größere Mengen dieser Moleküle …

New method for regioselective glycosylation employing saccharide oxyanions

M Matwiejuk, J Thiem - 2011 - Wiley Online Library
As an alternative concept for glycosylation, the prior activation of acceptor hydroxy groups
for selective glycosidic bond formation, was investigated to give complex oligosaccharides …

Thio-arylglycosides with various aglycon para-substituents: A probe for studying chemical glycosylation reactions

X Li, L Huang, X Hu, X Huang - Organic & biomolecular chemistry, 2009 - pubs.rsc.org
Three series of thioglycosyl donors differing only in their respective aglycon substituents
within each series have been prepared as representatives of typical glycosyl donors. The …