Decoding the fucose migration product during mass‐spectrometric analysis of blood group epitopes
Fucose is a signaling carbohydrate that is attached at the end of glycan processing. It is
involved in a range of processes, such as the selectin‐dependent leukocyte adhesion or …
involved in a range of processes, such as the selectin‐dependent leukocyte adhesion or …
Sunlight Induces the Production of Atmospheric Volatile Organic Compounds (VOCs) from Thermokarst Ponds
Ground subsidence caused by permafrost thawing causes the formation of thermokarst
ponds, where organic compounds from eroding permafrost accumulate. We photolyzed …
ponds, where organic compounds from eroding permafrost accumulate. We photolyzed …
Studying the Key Intermediate of RNA Autohydrolysis by Cryogenic Gas‐Phase Infrared Spectroscopy
K Greis, C Kirschbaum, MI Taccone… - Angewandte Chemie …, 2022 - Wiley Online Library
Over the course of the COVID‐19 pandemic, mRNA‐based vaccines have gained
tremendous importance. The development and analysis of modified RNA molecules benefit …
tremendous importance. The development and analysis of modified RNA molecules benefit …
Direct Experimental Characterization of a Sialyl Cation
F Dahlmann, CE Griesbach… - … A European Journal, 2024 - Wiley Online Library
Sialic acids are monosaccharide residues involved in several biological processes.
Controlling the stereoselectivity of sialylation reactions is challenging and mechanistic …
Controlling the stereoselectivity of sialylation reactions is challenging and mechanistic …
Dearomatization drives complexity generation in freshwater organic matter
Dissolved organic matter (DOM) is one of the most complex, dynamic and abundant sources
of organic carbon, but its chemical reactivity remains uncertain,–. Greater insights into DOM …
of organic carbon, but its chemical reactivity remains uncertain,–. Greater insights into DOM …
Photooxidation of Nonanoic Acid by Molecular and Complex Environmental Photosensitizers
G Freeman-Gallant, EJ Davis, E Scholer… - The Journal of …, 2024 - ACS Publications
Photochemical aging and photooxidation of atmospheric particles play a crucial role in both
the chemical and physical processes occurring in the troposphere. In particular, the …
the chemical and physical processes occurring in the troposphere. In particular, the …
The impact of side-chain fluorination on proton-bound phenylalanine dimers: a cryogenic infrared spectroscopic study
The incorporation of fluorine into amino acids is an important strategy to produce tailored
building blocks with unique properties for peptide-based materials. Phenylalanine is …
building blocks with unique properties for peptide-based materials. Phenylalanine is …
Cryogenic infrared spectroscopy reveals remarkably short NH+⋯ F hydrogen bonds in fluorinated phenylalanines
M Safferthal, K Greis, R Chang… - Physical Chemistry …, 2023 - pubs.rsc.org
In past decades, hydrogen bonds involving organic fluorine have been a highly disputed
topic. Obtaining clear evidence for the presence of fluorine-specific interactions is generally …
topic. Obtaining clear evidence for the presence of fluorine-specific interactions is generally …
Hydrogen Tag Shifts as Vibrational Reporters for Positional Isomers of Formylphenides: Surprising Mobility of the Carbanion Center upon Collisional Decarboxylation …
OC Moss, T Schleif, JP Messinger… - The Journal of …, 2024 - ACS Publications
Infrared photodissociation of weakly bound “mass tags” is widely used to determine the
structures of ions by analyzing their vibrational spectra. Molecular hydrogen is a common …
structures of ions by analyzing their vibrational spectra. Molecular hydrogen is a common …
Entschlüsselung des Fucose‐Migrationsproduktes bei der Massenspektrometrischen Analyse von Blutgruppenepitopen
Fucose ist ein signalgebendes Kohlenhydrat, das am Ende der Glykosylierung angehängt
wird. Es ist an einer Reihe von Prozessen beteiligt, z. B. an der Selectin‐abhängigen …
wird. Es ist an einer Reihe von Prozessen beteiligt, z. B. an der Selectin‐abhängigen …