Conspectus Carbon dioxide (CO2) is not only a greenhouse gas and a common waste
product but also an inexpensive, readily available, and renewable carbon resource. It is an …

The transformation of carbon dioxide (CO2) into useful chemicals, advanced materials, and
energy is a long-standing challenge in both fundamental science and industry. In recent …

Carbon dioxide (CO2) is an important C1 source for the generation of important carboxylic
acids and derivatives. Stoichiometric and catalytic carboxylation of nucleophiles, including …

With the increasing awareness of sustainable chemistry and green chemistry,
photochemical CO2 fixation has drawn more and more attention in response to the need for …

A catalytic deaminative alkylation of unactivated olefins is described. The protocol is
characterized by its mild conditions, wide scope, including the use of ethylene as substrate …

Direct carboxylation of C–H bonds with CO2 represents an attractive strategy to synthesize
valuable carboxylic acids with high atom, step, and redox economy. Although great progress …

Herein, we report the direct carboxylation of unactivated secondary alkyl bromides enabled
by the merger of photoredox and nickel catalysis, a previously inaccessible endeavor in the …

Conspectus The ubiquity and importance of carboxylic acids and amides in peptides,
pharmaceuticals, agrochemicals, and synthetic materials has challenged chemists to design …

Remote difunctionalization of unactivated alkenes is challenging but a highly attractive tactic
to install two functional groups across long distances. Reported herein is the first remote …

Self‐sustained NiI/III cycles are established as a potentially general paradigm in photoredox
Ni‐catalyzed carbon–heteroatom cross‐coupling reactions through a strategy that allows us …