Strategies to quench quantum tunneling of magnetization in lanthanide single molecule magnets

A Swain, T Sharma, G Rajaraman - Chemical Communications, 2023 - pubs.rsc.org
Enhancing blocking temperature (TB) is one of the holy grails in Single Molecule Magnets
(SMMs), as any future potential application in this class of molecules is directly correlated to …

Radical ligand-containing single-molecule magnets

S Demir, IR Jeon, JR Long, TD Harris - Coordination Chemistry Reviews, 2015 - Elsevier
Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …

Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Lanthanide double-decker complexes functioning as magnets at the single-molecular level

N Ishikawa, M Sugita, T Ishikawa… - Journal of the …, 2003 - ACS Publications
Double-decker phthalocyanine complexes with Tb3+ or Dy3+ showed slow magnetization
relaxation as a single-molecular property. The temperature ranges in which the behavior …

Quantum tunneling of magnetization and related phenomena in molecular materials

D Gatteschi, R Sessoli - Angewandte Chemie International …, 2003 - Wiley Online Library
Molecules comprising a large number of coupled paramagnetic centers are attracting much
interest because they may show properties which are intermediate between those of simple …

First principles approach to the electronic structure, magnetic anisotropy and spin relaxation in mononuclear 3d-transition metal single molecule magnets

M Atanasov, D Aravena, E Suturina, E Bill… - Coordination Chemistry …, 2015 - Elsevier
In this review, a self-contained (although brief) introduction to electronic structure
calculations for single molecule magnet (SMM) properties is provided in conjunction with …

Molecular dynamics simulation of the ice nucleation and growth process leading to water freezing

M Matsumoto, S Saito, I Ohmine - Nature, 2002 - nature.com
Upon cooling, water freezes to ice. This familiar phase transition occurs widely in nature, yet
unlike the freezing of simple liquids,,, it has never been successfully simulated on a …

Single-molecule magnets

G Christou, D Gatteschi, DN Hendrickson, R Sessoli - MRS bulletin, 2000 - cambridge.org
Magnets are widely used in a large number of applications, and their market is larger than
that of semiconductors. Information storage is certainly one of the most important uses of …

Giant single-molecule magnets: a Mn84 torus and its supramolecular nanotubes

AJ Tasiopoulos, A Vinslava, W Wernsdorfer… - arxiv preprint cond-mat …, 2004 - arxiv.org
The discovery a decade ago that individual molecules can function as magnetizable
magnets provided a new,'bottom-up'approach to nanoscale magnetic materials, and such …

Exchange-biased quantum tunnelling in a supramolecular dimer of single-molecule magnets

W Wernsdorfer, N Aliaga-Alcalde, DN Hendrickson… - Nature, 2002 - nature.com
Various present and future specialized applications of magnets require monodisperse, small
magnetic particles, and the discovery of molecules that can function as nanoscale magnets …