Nitrogen fixation, the six-electron/six-proton reduction of N2, to give NH3, is one of the most
challenging and important chemical transformations. Notwithstanding the barriers …

The large carbon footprint of the Haber–Bosch process, which provides ammonia for
fertilizers but also the feedstock for all nitrogenous commercial products, has fueled the …

Biological nitrogen fixation by the nitrogenase enzymes has long been a touchstone for
dinitrogen chemists. 1, 2 Both the enzymatic reduction and protonation of N2 mediated by …

Sonodynamic therapy (SDT), a combination of low-intensity ultrasound with a
sonosensitizer, has been explored as a promising alternative for cancer therapy. However …

This review attempts to survey the recent literature concerning the coordination chemistry
and the reactivity patterns of metal–dinitrogen complexes. In order that this work may stand …

The activation of dinitrogen by coordination to transition metal ions is a widely used and
promising approach to the utilization of Earth's most abundant nitrogen source for chemical …

Despite advances in the development of molecular catalysts capable of reducing dinitrogen
to ammonia using proton donors and chemical reductants, few molecular electrocatalysts …

[ReCl3 (PPh3) 2 (NCMe)] reacts with pincer ligand HN (CH2CH2P t Bu2) 2 (H PNP) to five
coordinate rhenium (III) complex [ReCl2 (PNP)]. This compound cleaves N2 upon reduction …

Terminal and bridging end-on coordination of N2 to transition metal complexes offer
possibilities for distinct pathways in ammonia synthesis and N2 functionalization. Here we …

A comprehensive mechanistic study of N2 activation and splitting into terminal nitride
ligands upon reduction of the rhenium dichloride complex [ReCl2 (PNP)] is presented (PNP …