Catalysis of alloys: classification, principles, and design for a variety of materials and reactions

Y Nakaya, S Furukawa - Chemical Reviews, 2022 - ACS Publications
Alloying has long been used as a promising methodology to improve the catalytic
performance of metallic materials. In recent years, the field of alloy catalysis has made …

[HTML][HTML] Magic of hydrogen spillover: Understanding and application

H Shen, H Li, Z Yang, C Li - Green Energy & Environment, 2022 - Elsevier
The hydrogen spillover effect (HSPE) plays an important role in heterogeneous catalysis
and hydrogen storage as an interfacial phenomenon, which facilitates the improvement of …

Gradient Hydrogen Migration Modulated with Self-Adapting S Vacancy in Copper-Doped ZnIn2S4 Nanosheet for Photocatalytic Hydrogen Evolution

S Zhang, Z Zhang, Y Si, B Li, F Deng, L Yang, X Liu… - ACS …, 2021 - ACS Publications
It is a challenge to regulate charge flow synergistically at the atomic level to modulate
gradient hydrogen migration (H migration) for boosting photocatalytic hydrogen evolution …

Hydrogen spillover-driven synthesis of high-entropy alloy nanoparticles as a robust catalyst for CO2 hydrogenation

K Mori, N Hashimoto, N Kamiuchi, H Yoshida… - Nature …, 2021 - nature.com
High-entropy alloys (HEAs) have been intensively pursued as potentially advanced
materials because of their exceptional properties. However, the facile fabrication of …

Revealing hydrogen spillover pathways in reducible metal oxides

K Shun, K Mori, S Masuda, N Hashimoto, Y Hinuma… - Chemical …, 2022 - pubs.rsc.org
Hydrogen spillover, the migration of dissociated hydrogen atoms from noble metals to their
support materials, is a ubiquitous phenomenon and is widely utilized in heterogeneous …

Precious-metal-free Mo-MXene catalyst enabling facile ammonia synthesis via dual sites bridged by H-spillover

Y Zhou, L Liang, C Wang, F Sun, L Zheng… - Journal of the …, 2024 - ACS Publications
To date, NH3 synthesis under mild conditions is largely confined to precious Ru catalysts,
while nonprecious metal (NPM) catalysts are confronted with the challenge of low catalytic …

Heteroatom do** enables hydrogen spillover via H+/e diffusion pathways on a non-reducible metal oxide

K Shun, K Mori, T Kidawara, S Ichikawa… - Nature …, 2024 - nature.com
Hydrogen spillover, the simultaneous diffusion of protons (H+) and electrons (e−) is
considered to be applicable to ubiquitous technologies related to hydrogen but limited to …

Unveiling the bifunctional modulation evoked by bromine do** of CoP towards efficient hydrolytic hydrogen generation

C Yuan, T Xu, M Guo, Y Sun, T Zhang, X Yu - Applied Catalysis B …, 2024 - Elsevier
Develo** efficient and economical catalysts for hydrolytic hydrogen production from
chemical hydrogen storage materials such as ammonia borane and NaBH 4 is highly …

Structure-performance correlation on bimetallic catalysts for selective CO 2 hydrogenation

S Zou, L Wang, H Wang, X Zhang, H Sun… - Energy & …, 2023 - pubs.rsc.org
CO2 hydrogenation to C1 chemicals has attracted significant interest due to the increasing
demand for energy and global warming. Continuous efforts in the field of heterogeneous …

Ultrasonic-assisted hydrothermal synthesis of RhCu alloy nanospheres for electrocatalytic urea production

S Fu, K Chu, M Guo, Z Wu, Y Wang, J Yang… - Chemical …, 2023 - pubs.rsc.org
Herein, the electronic structure of RhCu nanospheres was optimized and the size of the
nanoparticles was reduced by an ultrasonic-assisted hydrothermal method. The …