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Chemical flexibility of atomically precise metal clusters
S Li, NN Li, XY Dong, SQ Zang, TCW Mak - Chemical Reviews, 2024 - ACS Publications
Ligand-protected metal clusters possess hybrid properties that seamlessly combine an
inorganic core with an organic ligand shell, imparting them exceptional chemical flexibility …
inorganic core with an organic ligand shell, imparting them exceptional chemical flexibility …
N-Heterocyclic Carbene-Stabilized Atomically Precise Metal Nanoclusters
This perspective highlights advances in the preparation and understanding of metal
nanoclusters stabilized by organic ligands with a focus on N-heterocyclic carbenes (NHCs) …
nanoclusters stabilized by organic ligands with a focus on N-heterocyclic carbenes (NHCs) …
Frontiers in circularly polarized luminescence: molecular design, self-assembly, nanomaterials, and applications
The research in circularly polarized luminescence has attracted wide interest in recent
years. Efforts on one side are directed toward the development of chiral materials with both …
years. Efforts on one side are directed toward the development of chiral materials with both …
In situ reconstruction to surface sulfide adsorbed metal scaffold for enhanced electrocatalytic hydrogen evolution activity
Transition‐metal‐based compounds have been intensively explored as efficient
electrocatalysts for hydrogen evolution reaction (HER). Feasible reconstruction to the real …
electrocatalysts for hydrogen evolution reaction (HER). Feasible reconstruction to the real …
Atomically precise alloy nanoclusters: syntheses, structures, and properties
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …
providing unique opportunities for investigating the quantum effects and precise structure …
N-Heterocyclic Carbene-Stabilized Hydrido Au24 Nanoclusters: Synthesis, Structure, and Electrocatalytic Reduction of CO2
Atomically precise hydrido gold nanoclusters are extremely rare but interesting due to their
potential applications in catalysis. By optimization of molecular precursors, we have …
potential applications in catalysis. By optimization of molecular precursors, we have …
Metal Single‐Atom Cocatalyst on Carbon Nitride for the Photocatalytic Hydrogen Evolution Reaction: Effects of Metal Species
Single‐atom (SA) catalysts exhibit high activity in various reactions because there are no
inactive internal atoms. Accordingly, SA cocatalysts are also an active research fields …
inactive internal atoms. Accordingly, SA cocatalysts are also an active research fields …
Ligand‐Shell Engineering of a Au28 Nanocluster Boosts Electrocatalytic CO2 Reduction
Subtle tailoring of gold nanoclusters (NCs) could significantly change their physicochemical
properties. However, direct comparison of the catalytic performance of gold NCs with …
properties. However, direct comparison of the catalytic performance of gold NCs with …
Atomically precise metal nanoclusters as catalysts for electrocatalytic CO 2 reduction
Electrochemical carbon dioxide (CO2) reduction can be used to convert CO2 into various
compounds at room temperature and ambient pressure using electricity generated from …
compounds at room temperature and ambient pressure using electricity generated from …
Unraveling the impact of gold (I)–thiolate motifs on the aggregation‐induced emission of gold nanoclusters
Aggregation‐induced emission (AIE) provides an efficient strategy to synthesize highly
luminescent metal nanoclusters (NCs), however, rational control of emission energy and …
luminescent metal nanoclusters (NCs), however, rational control of emission energy and …