Several mechanisms have been proposed to interpret the widely reported phenomenon of
Mg corrosion that the hydrogen evolution rate increases with increasing anodic potential or …

It is likely that reactions of magnesium metal with organic halides RX in ether solvents are
typical metallic corrosions in which the stabilization of Mg2+, substantially through its …

A rhodium-catalyzed coupling reaction of 2-trimethylsilylphenylboronic acid with internal
alkynes is developed for the synthesis of 2, 3-disubstituted benzosilole derivatives. A range …

In comparison with all-carbon parent compounds, the incorporation of Si-element into
carboskeletons generally endows the corresponding sila-analogues with unique biological …

The chemistry of organosilicon compounds has been one of the indispensable and
inseparable parts of synthetic organic transformations. The synthesis of new silicon reagents …

An efficient process involving Pd-catalyzed selective cleavage of a C (sp3)–Si bond and
consequent intramolecular C (sp2)–Si coupling has been developed, affording benzosilolo …

The reaction of 2-(trimethylsilyl) phenylboronic acid with alkynes in the presence of a
rhodium catalyst affords benzosilole derivatives. The arylvinylrhodium intermediate …

On-surface synthesis is a powerful method that has emerged recently to fabricate a large
variety of atomically precise nanomaterials on surfaces based on polymerization. It is very …

The organocalcium chemistry developed vastly during the last decade. The preparation of
the organocalcium compounds via direct synthesis (insertion of Ca into a C‐X bond of …

Silicon-bridged 1, 6-diynes underwent [2+ 2+ 2] cycloaddition with alkynes in the presence
of an iridium (I)− phosphine catalyst to afford densely substituted silafluorene derivatives …