Rise of conjugated poly-ynes and poly (metalla-ynes): from design through synthesis to structure–property relationships and applications

A Haque, RA Al-Balushi, IJ Al-Busaidi, MS Khan… - Chemical …, 2018 - ACS Publications
Conjugated poly-ynes and poly (metalla-ynes) constitute an important class of new materials
with potential application in various domains of science. The key factors responsible for the …

Functionalization of oxide-free silicon surfaces with redox-active assemblies

B Fabre - Chemical Reviews, 2016 - ACS Publications
This review provides a comprehensive survey of the derivatization of hydrogen-terminated,
oxide-free silicon surfaces with electroactive assemblies (from molecules to polymers) …

Charge delocalization vs localization in carbon-rich iron mixed-valence complexes: A subtle interplay between the carbon spacer and the (dppe) Cp* Fe …

JF Halet, C Lapinte - Coordination Chemistry Reviews, 2013 - Elsevier
In this review, the electronic and structural properties of different organometallic wires
containing the (dppe) Cp* Fe organometallic electrophore are thoroughly discussed. Results …

Polynuclear carbon-rich organometallic complexes: clarification of the role of the bridging ligand in the redox properties

K Costuas, S Rigaut - Dalton Transactions, 2011 - pubs.rsc.org
In this Perspective, we highlight the non-innocent behaviour of the bridging ligand in
organometallic polynuclear metallic complexes displaying metal-carbon σ bonds between …

Twists and turns: Studies of the complexes and properties of bimetallic complexes featuring phenylene ethynylene and related bridging ligands

PJ Low - Coordination Chemistry Reviews, 2013 - Elsevier
The concept of a molecular-based electronic technology has been evolving for over 50
years, and the development of molecular designs for such components over this period has …

enantio-Enriched CPL-active helicene–bipyridine–rhenium complexes

N Saleh, M Srebro, T Reynaldo, N Vanthuyne… - Chemical …, 2015 - pubs.rsc.org
The incorporation of a rhenium atom within an extended helical π-conjugated bi-pyridine
system impacts the chiroptical and photophysical properties of the resulting neutral or …

Metal complexes with non-innocent ligands

KP Butin, EK Beloglazkina, NV Zyk - Russian chemical reviews, 2005 - iopscience.iop.org
The review summarises data on transition metal complexes with the so-called non-innocent
ligands. The specific feature of these complexes is that the oxidation state of the central …

Synthesis and characterization of luminescent rhenium (I) tricarbonyl diimine complexes with a triarylboron moiety and the study of their fluoride ion-binding properties

ST Lam, N Zhu, VWW Yam - Inorganic chemistry, 2009 - ACS Publications
A series of alkynylrhenium (I) tricarbonyl diimine complexes with a triarylboron moiety has
been synthesized and characterized. The binding properties of the complex toward fluoride …

Bonding and substituent effects in electron-rich mononuclear ruthenium σ-Arylacetylides of the formula [(η2-dppe)(η5-C5Me5) Ru (C⋮ C)-1, 4-(C6H4) X][PF6] n (n= 0 …

F Paul, BG Ellis, MI Bruce, L Toupet, T Roisnel… - …, 2006 - ACS Publications
This study reports the isolation and the structural (X-ray), UV− vis, and NMR characterization
of a series of electron-rich Ru (II) acetylide complexes of the formula (η2-dppe)(η5-C5Me5) …

Ruthenium complexes with vinyl, styryl, and vinylpyrenyl ligands: a case of non-innocence in organometallic chemistry

J Maurer, M Linseis, B Sarkar… - Journal of the …, 2008 - ACS Publications
We herein describe a systematic account of mononuclear ruthenium vinyl complexes
L−{Ru}− CH CH− R where the phosphine ligands at the (PR '3) 2Ru (CO) Cl {Ru} moiety, the …