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Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
Mechanistic studies in photocatalysis
The fast‐moving fields of photoredox and photocatalysis have recently provided fresh
opportunities to expand the potential of synthetic organic chemistry. Advances in light …
opportunities to expand the potential of synthetic organic chemistry. Advances in light …
Photoinduced Halogen-Atom Transfer by N-Heterocyclic Carbene-Ligated Boryl Radicals for C(sp3)–C(sp3) Bond Formation
Herein, we present a comprehensive study on the use of N-heterocyclic carbene (NHC)-
ligated boryl radicals to enable C (sp3)–C (sp3) bond formation under visible-light irradiation …
ligated boryl radicals to enable C (sp3)–C (sp3) bond formation under visible-light irradiation …
Direct excitation strategy for radical generation in organic synthesis
Y Sumida, H Ohmiya - Chemical Society Reviews, 2021 - pubs.rsc.org
Visible-light-mediated chemical processes have been vigorously studied and have led to
state-of-the-art synthetic chemistry since they enable the control of radical generation and …
state-of-the-art synthetic chemistry since they enable the control of radical generation and …
Applications of continuous-flow photochemistry in organic synthesis, material science, and water treatment
Continuous-flow photochemistry in microreactors receives a lot of attention from researchers
in academia and industry as this technology provides reduced reaction times, higher …
in academia and industry as this technology provides reduced reaction times, higher …
A beginners guide to understanding the mechanisms of photochemical reactions: things you should know if light is one of your reagents
JC Scaiano - Chemical Society Reviews, 2023 - pubs.rsc.org
The increasing popularity of applied photochemistry has changed the composition of the
practitioners of photochemistry, from traditional specialists, to users whose expertise lies …
practitioners of photochemistry, from traditional specialists, to users whose expertise lies …
Photons as a 21st century reagent
A pharmaceutical industry viewpoint on how the fundamental laws of photochemistry are
used to identify the parameters required to implement photochemistry from lab to scale …
used to identify the parameters required to implement photochemistry from lab to scale …
Nitrative difunctionalization of alkenes via cobalt-mediated radical ligand transfer and radical-polar crossover photoredox catalysis
Herein, we report the rational design of a modular dual photoredox and cobalt catalysis
paradigm for the difunctionalization of unsaturated hydrocarbons, unlocking the synthesis of …
paradigm for the difunctionalization of unsaturated hydrocarbons, unlocking the synthesis of …
Mechanistic perspectives on organic photoredox catalysis for aromatic substitutions
Conspectus Photoredox catalysis has emerged as a powerful tool for the utilization of visible
light to drive chemical reactions between organic molecules that exhibit two rather …
light to drive chemical reactions between organic molecules that exhibit two rather …
A case of chain propagation: α-aminoalkyl radicals as initiators for aryl radical chemistry
The generation of aryl radicals from the corresponding halides by redox chemistry is
generally considered a difficult task due to their highly negative reduction potentials. Here …
generally considered a difficult task due to their highly negative reduction potentials. Here …